Skip to main content
Log in

Growth of vertically aligned ZnO nanorods on Teflon as a novel substrate for low-power flexible light sensors

  • Rapid communication
  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

In this work, vertically aligned zinc oxide (ZnO) nanorods were successfully grown by a wet chemical bath deposition method on a ZnO seed-layer-coated Teflon substrate at room temperature. The strong and sharp (0 0 2) peak in the XRD pattern along with the calculated low compressive strain indicated the vertical growth of high-quality crystalline ZnO nanorods along the z-axis on the substrate. The field emission scanning electron microscopy images show the ZnO nanorods to have diameters ranging from 34 to 52 nm. Raman analyses revealed a high E2 (high) peak at 440.23 nm. A flexible ZnO nanorod-based metal–semiconductor–metal UV detector was fabricated. The device showed a sensitivity of 1466. The responsivity (R) of the device is 2.265 A/W, which is 20 times higher than that reported for ZnO-based PDs. Under low power illumination (370 nm, 1.5 mW/cm2), the device showed a relatively fast response and baseline recovery for UV detection. The prototype device shows a simple method for nanorod synthesis and demonstrates the possibility of constructing nanoscale photodetectors for nano-optics applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

References

  1. A. Kołodziejczak-Radzimska, T. Jesionowski, Zinc oxide—from synthesis to application: a review. Materials 7, 2833–2881 (2014)

    Article  ADS  Google Scholar 

  2. Y. Chen, D. Bagnall, H.K. Park, K. Hiraga, Z. Zhu, T. Yao, Plasma assisted molecular beam epitaxy of ZnO on c-plane sapphire: growth and characterization. J. Appl. Phys. 84, 3912–3918 (1989)

    Article  ADS  Google Scholar 

  3. A. Singh, D. Kumar, P.K. Khanna, A. Kumar, M. Kumar, M. Kumar, Thin Solid Films 519, 5826 (2011)

    Article  ADS  Google Scholar 

  4. N. Samir, D.S. Eissa, N.K. Allam, Self-assembled growth of vertically aligned ZnO nanorods for light sensing applications. Mater. Lett. 137, 45–48 (2014)

    Article  Google Scholar 

  5. F. Xu, M. Dai, Y.N. Lu, L.T. Sun, Hierarchical ZnO nanowire–nanosheet architectures for high power conversion efficiency in dye-sensitized solar cells. J. Phys. Chem. C 114, 2776 (2010)

    Article  Google Scholar 

  6. G. Chansin, printed and flexible sensors 2014–2024: technologies, players, forecasts. IDTechEx, http://www.idtechex.com/research/reports/printed-and-flexible-sensors-2014-2024-technologies-players-forecasts-000367.asp

  7. R. Shabannia, H. Abu Hassan, Controllable vertically aligned ZnO nanorods on flexible polyethylene naphthalate (PEN) substrate using chemical bath deposition synthesis. Appl. Phys. A 114, 579–584 (2014)

    Article  ADS  Google Scholar 

  8. E.L. Bedia, S. Murakami, T. Kitade, S. Kohjiya, Structural development and mechanical properties of polyethylene naphthalate/polyethylene terephthalate blends during uniaxial drawing. Polymer 42, 7299–7305 (2001)

    Article  Google Scholar 

  9. G. Shen, Y. Bando, C.-J. Lee, Growth of self-organized hierarchical ZnO nanoarchitectures by a simple In/In2S3 controlled thermal evaporation process. J. Phys. Chem. B 109, 10779–10785 (2005)

    Article  Google Scholar 

  10. S. Xu, N. Adiga, S. Ba, T. Dasgupta, C.F.J. Wu, Z.L. Wang, Optimizing, improving the growth quality of ZnO nanowire arrays guided by statistical design of experiments. ACS Nano 3, 1803–1812 (2009)

    Article  Google Scholar 

  11. O.F. Farhat, M.M. Halim, M.J. Abdullah, M.K.M. Ali, N.K. Allam, Morphological and structural characterization of single-crystal ZnO nanorod arrays on flexible and non-flexible substrates. Beilstein J. Nanotechnol. 6, 720–725 (2015)

    Article  Google Scholar 

  12. J.J. Hassan, Z. Hassan, H. Abu-Hassan, High-quality vertically aligned ZnO nanorods synthesized by microwave-assisted CBD with ZnO–PVA complex seed layer on Si substrates. J. Alloys Compd. 509, 6711–6719 (2011)

    Article  Google Scholar 

  13. A. Goux, T. Pauporté, J. Chivot, D. Lincot, Temperature effects on ZnO electrodeposition. Electrochim. Acta 50, 2239–2248 (2005)

    Article  Google Scholar 

  14. X. Zhu, H. Wu, Z. Yuan, J. Kong, W. Shen, Multiphonon resonant Raman scattering in N-doped ZnO. J. Raman Spect. 40, 2155–2161 (2009)

    Article  ADS  Google Scholar 

  15. Shuxia Guo, Du Zuliang, Shuxi Dai, Analysis of Raman modes in Mn-doped ZnO nanocrystals. Phys. Status Solidi B 246, 2329–2332 (2009)

    Article  ADS  Google Scholar 

  16. L. Li, P. Wu, X. Fang, T. Zhai, L. Dai, M. Liao, Y. Koide, H. Wang, Y. Bando, D. Golberg, Single-crystalline CDS nanobelts for excellent field-emitters and ultrahigh quantum-efficiency photodetectors. Adv. Mater. 22, 3161–3165 (2010)

    Article  Google Scholar 

  17. N.K. Hassan, M.R. Hashim, N.K. Allam, Low power UV photodetection characteristics of cross-linked ZnO nanorods/nanotetrapods grown on silicon chip. Sens. Actuators, A 192, 124–129 (2013)

    Article  Google Scholar 

  18. L.W. Ji, S.M. Peng, Y.K. Su, S.J. Young, C.Z. Wu, W.B. Cheng, Ultraviolet photodetectors based on selectively grown ZnO nanorod arrays. Appl. Phys. Lett. 94, 203106 (2009)

    Article  ADS  Google Scholar 

  19. B. Yuan, X.J. Zheng, Y.Q. Chen, B. Yang, T. Zhang, High photosensitivity and low dark current of photoconductive semiconductor switch based on ZnO single nanobelt. Solid State Electron. 55, 49–53 (2011)

    Article  ADS  Google Scholar 

  20. J.J. Hassan, M.A. Mahdi, S.J. Kasim, N.M. Ahmed, H. Abu Hassan, Z. Hassan, High sensitivity and fast response and recovery times in a ZnO nanorod array/p-Si self-powered ultraviolet detector. Appl. Phys. Lett. 101, 261108 (2012)

    Article  ADS  Google Scholar 

  21. S.K. Mishra, S. Bayan, Defect-dominated optical emission and enhanced ultraviolet photoconductivity properties of ZnO nanorods synthesized by simple and catalyst-free approach. Appl. Phys. A 115, 1193 (2014)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Nageh K. Allam.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Farhat, O.F., Halim, M.M., Abdullah, M.J. et al. Growth of vertically aligned ZnO nanorods on Teflon as a novel substrate for low-power flexible light sensors. Appl. Phys. A 119, 1197–1201 (2015). https://doi.org/10.1007/s00339-015-9177-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-015-9177-1

Keywords

Navigation