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Thermal, vibrational spectra and photoluminescence properties of the nonlinear optical material MnTeMoO6

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Abstract

MnTeMoO6 is a novel nonlinear optical material in near-mid-IR region. Vibrational spectra characterization, thermal and photoluminescent properties of polycrystalline MnTeMoO6 have been investigated in this work. The results show that polycrystalline MnTeMoO6 has a relatively high melting point at 725.2 °C and exhibits superheating of crystal. The observed Raman and IR bands of MnTeMoO6 are assigned to vibrations of the Mn–O bonds, MoO4 tetrahedra, and TeO4 polyhedra. Photoluminescence measurements show that MnTeMoO6 displays a strong emission peak at 467 nm under excitation at 280 nm, and the absorption band at 0.47–0.52 μm in UV–vis spectra may be caused by photoluminescence.

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Acknowledgments

The authors thank Professor Yujun Liang for his great help with photo-luminescence measurements.

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Authors and Affiliations

  1. Key Laboratory of Computational Physics of Sichuan Province, Yibin University, Yibin, 644000, China

    Chengguo Jin, Juxiang Shao, Junsheng Yang, Qilong Cao, Duohui Huang, Mingjie Wan & Fanhou Wang

  2. Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, 430074, China

    Zhen Li

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  1. Chengguo Jin
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  2. Juxiang Shao
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  3. Zhen Li
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  4. Junsheng Yang
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  5. Qilong Cao
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  8. Fanhou Wang
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Correspondence to Chengguo Jin.

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Jin, C., Shao, J., Li, Z. et al. Thermal, vibrational spectra and photoluminescence properties of the nonlinear optical material MnTeMoO6 . Appl. Phys. A 119, 121–125 (2015). https://doi.org/10.1007/s00339-015-8989-3

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  • DOI: https://doi.org/10.1007/s00339-015-8989-3

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