Abstract
Grafting of binary vinyl monomer mixtures such as 2-methylpropenoic acid (MPA) and acrylonitrile (AN) onto poly (ethylene terephthalate) fibers (PET) was achieved in an aqueous medium with using benzoyl peroxide like free radical initiator. A new reactively fibrous adsorbent was used for removal of dye such as methylene blue (MB) from aqueous media through batch sorption method. Fibers adsorbent was swelled in solution to support the graft and the subsequent polymerization of MPA/AN onto polyester fibers. Optimum conditions for grafting were discovered and reactive fiber were characterized. Variations of graft yield with time, temperature, initiator concentration and monomer mixture ratio were investigated. The optimum initiator concentration was found to be 8 × 10−3 mol/L. The percentage of grafting rose steadily with the vinyl monomer mixture monomer concentration (50 %). The optimum temperature and polymerization time were found to be 80 °C and 120 min, respectively. The use of AN and MPA monomers together in grafting produce a significant increased in the graft yield. Experimental studies showed that the percentage removal of MB was a great higher on the MPA/AN grafted PET (MPA/AN-g-PET) fibers than on the original PET fibers. The adsorbed quantity of MB improved with pH and basic pH was appropriate for the elimination of MB. MPA/AN-g-PET fibers removed 98 % of cationic dye when initial concentration diverse from 10 to 80 mg L−1 at pH 9.0. Almost all of the adsorbed cationic dye was eluted by ethanoic acid in methanol. Ten removal–desorption cycles indicated that the reactive fibers were favorable for repetitive use without notable change in removal capacity. Consequently, the MPA/AN-g-PET fibers have demonstrated potential as an effective adsorbent for the extremely effective removal of cationic dyes from aqueous media.
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References
Yagub MT, Sen TK, Afroze S, Ang HM (2014) Dye and its removal from aqueous solution by adsorption: a review. Adv Colloid Interf 209:172–184
Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Bioresour Technol 97(9):1061–1085
Forgacs E, Cserhati T, Oros G (2004) Removal of synthetic dyes from wastewaters: a review. Environ Int 30(7):953–971
Ong ST, Lee CK, Zainal Z (2007) Removal of basic and reactive dyes using ethylenediamine modified rice hull. Bioresour Technol 98(15):2792–2799
Anliker R, Clarke EA (1980) The ecology and toxicology of synthetic organic pigments. Chemosphere 9(10):595–609
MajcenLeMarechal A, Slokar YM, Taufer T (1997) Decoloration of chlorotriazine reactive azo dyes with H2O2/UV. Dyes Pigments 33(4):281–298
Banat IM, Nigam P, Singh D, Marchant R (1996) Microbial decolorization of textile-dye-containing effluents: a review. Bioresour Technol 58(3):217–227
Kannan N, Sundaram MM (2001) Kinetics and mechanism of removal of methylene blue by adsorption on various carbons—a comparative study. Dyes Pigments 51(1):25–40
Chafi M, Gourich B, Essadki AH, Vial C, Fabregat A (2011) Comparison of electrocoagulation using iron and aluminium electrodes with chemical coagulation for the removal of a highly soluble acid dye. Desalination 281:285–292
Garcia-Gabaldon M, Perez-Herranz V, Garcia-Anton J, Guinon JL (2006) Electrochemical recovery of tin from the activating solutions of the electroless plating of polymers Galvanostatic operation. Sep Purif Technol 51(2):143–149
Zeng GM, Cheng M, Huang DL, Lai C, Xu PA, Wei Z et al (2015) Study of the degradation of methylene blue by semi-solid-state fermentation of agricultural residues with Phanerochaete chrysosporium and reutilization of fermented residues. Waste Manage 38:424–430
Sohrabi MR, Ghavami M (2008) Photocatalytic degradation of direct red 23 dye using UV/TiO2: effect of operational parameters. J Hazard Mater 153(3):1235–1239
Arslan M (2011) Immobilization horseradish peroxidase on amine-functionalized glycidyl methacrylate-g-poly(ethylene terephthalate) fibers for use in azo dye decolorization. Polym Bull 66(7):865–879
Abdullah AZ, Salamatinia B, Kamaruddin AH (2009) Application of response surface methodology for the optimization of NaOH treatment on oil palm frond towards improvement in the sorption of heavy metals. Desalination 244(1–3):227–238
Doke SM, Yadav GD (2014) Novelties of combustion synthesized titania ultrafiltration membrane in efficient removal of methylene blue dye from aqueous effluent. Chemosphere 117:760–765
Yuan Q, Chen L, Xiong M, He J, Luo SL, Au CT et al (2014) Cu2O/BiVO4 heterostructures: synthesis and application in simultaneous photocatalytic oxidation of organic dyes and reduction of Cr(VI) under visible light. Chem Eng J 255:394–402
Mohammadi T, Razmi A, Sadrzadeh M (2004) Effect of operating parameters on Pb2+ separation from wastewater using electrodialysis. Desalination 167(1–3):379–385
Yigitoglu M, Arslan M (2005) Adsorption of hexavalent chromium from aqueous solutions using 4-vinyl pyridine grafted poly(ethylene terephthalate) fibers. Polym Bull 55(4):259–268
Rafatullah M, Sulaiman O, Hashim R, Ahmad A (2010) Adsorption of methylene blue on low-cost adsorbents: a review. J Hazard Mater 177(1–3):70–80
Asamoto H, Kimura Y, Ishiguro Y, Minamisawa H, Yamada K (2016) Use of polyethylene films photografted with 2-(dimethylamino)ethyl methacrylate as a potential adsorbent for removal of chromium (VI) from aqueous medium. J Appl Polym Sci 133(18):43360–43370
Gupta VK, Suhas (2009) Application of low-cost adsorbents for dye removal—a review. J Environ Manage 90(8):2313–2342
Coskun R (2011) Removal of cationic dye from aqueous solution by adsorption onto crosslinked poly(4-vinylpyridine/crotonic acid) and its N-oxide derivative. Polym Bull 67(1):125–140
Nesic AR, Panic VV, Onjia AE, Velickovic SJ (2015) The enhanced removal of cationic dyes in binary system using novel copolymers with two kinds of acidic groups. Colloid Surf A 476:24–34
Arslan M, Yigitoglu M (2008) Use of methacrylic acid grafted poly(ethylene terephthalate) fibers for the removal of basic dyes from aqueous solutions. J Appl Polym Sci 110(1):30–38
Yigitoglu M, Arslan M (2007) 4-vinylpyridine and 2-hydroxyethylmethacrylate monomer mixture graft copolymerization onto poly(ethylene terephthalate) fibers using benzoyl peroxide. Polym Bull 58(5–6):785–798
Arslan M (2010) Kinetics of graft copolymerization of acrylamide and 2-hydroxyethylmethacrylate monomer mixture onto poly(ethylene terephthalate) fibers. Korean J Chem Eng 27(3):991–998
Arslan M (2011) Preparation and application of glycidyl methacrylate and methacrylic acid monomer mixture-grafted poly(ethylene terephthalate) fibers for removal of methylene blue from aqueous solution. J Appl Polym Sci 119(5):3034–3042
Coskun R, Sacak M, Karakisla M (2005) Graft copolymerization of an itaconic acid/acrylamide monomer mixture onto poly(ethylene terephthalate) fibers with benzoyl peroxide. J Appl Polym Sci 97(5):1795–1803
Coskun R, Soykan C, Sacak M (2006) Adsorption of copper(II), nickel(II) and cobalt(II) ions from aqueous solution by methacrylic acid/acrylamide monomer mixture grafted poly(ethylene terephthalate) fiber. Sep Purif Technol 49(2):107–114
Coskun R, Akdeniz S (2010) Functinalization of poly(ethylene terephthalate) fibers by grafting of maleic acid/methacrylamide monomer mixture. Fiber Polym 11(8):1111–1118
Yigitoglu M, Arslan M (2007) Adsorption behaviour of methylene blue from aqueous solution on poly(ethylene terephthalate)-g-4-vinylpyridine/2-hydroxyethylmethacrylate fibers. E Polym 55:1–15
Wang L, Li Q, Wang AQ (2010) Adsorption of cationic dye on N, O-carboxymethyl-chitosan from aqueous solutions: equilibrium, kinetics, and adsorption mechanism. Polym Bull 65(9):961–975
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Arslan, M., Günay, K. Synthesis and characterization of PET fibers grafted with binary mixture of 2-methylpropenoic acid and acrylonitrile by free radical: its application in removal of cationic dye. Polym. Bull. 74, 1221–1236 (2017). https://doi.org/10.1007/s00289-016-1773-5
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DOI: https://doi.org/10.1007/s00289-016-1773-5