Abstract
Spray drying was investigated as a strategy for producing single wall carbon nanotube (SWCNT)/polymer composites. The spray-drying method produced SWCNT/poly(3-hydroxybutyrate) and SWCNT/poly(3-hydroxyoctanoate) composite particles in which the SWCNTs have been trapped in a well-dispersed state throughout the polymer matrix. Increasing SWCNT content in the composite led to a change in particle morphology from spherical and smooth to rosette shape with angular distortions. The technique shows potential for bulk carbon composite fabrication.
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Supronowicz PR, Ajayan PM, Ullmann KR, Arulanandam BP, Metzger DW, Bizios RJ (2002) Novel current-conducting composite substrates for exposing osteoblasts to alternating current stimulation. Biomed Mater Res 59:499–506
Correa-Duarte MA, Wagner N, Rojas-Chapana J, Morsczeck C, Thie M, Giersig M (2004) Fabrication and biocompatibility of carbon nanotube-based 3D networks as scaffolds for cell seeding and growth. Nano Lett 4:2233–2236
Song W, Zheng Z, Tang W, Wang X (2007) A facile approach to covalently functionalized carbon nanotubes with biocompatible polymer. Polymer 48:3658–3663
Yun SI, Gadd GE, Latella BA, Lo V, Russell RA, Holden PJ (2008) Mechanical properties of biodegradable polyhydroxyalkanoates/single Wall carbon nanotube nanocomposite films. Polym Bull 61:267–275
Moniruzzaman M, Winey KI (2007) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39:5194–5205
Ajayan PM, Tour JM (2007) Nanotube composites. Nature 447:1066–1068
Tran MQ, Shaffer MSP, Bismarck A (2008) Manufacturing carbon nanotube/PVDF nanocomposite powders. Macromol Mater Eng 293:188–193
Sudesh K, Abe H, Doi Y (2000) Synthesis, structure and properties of polyhydroxyalkanoates: biological polyesters. Prog Polym Sci 25:1503–1555
Chen GQ, Wu Q (2005) Polyhydroxyalkanoates as tissue engineering materials. Biomaterials 26:6565–6578
Misra SK, Valappil SP, Roy I, Boccaccini AR (2006) Polyhydroxyalkanoate (PHA)/inorganic phase composites for tissue engineering applications. Biomacromolecules 7:2249–2258
Vehring R (2007) Pharmaceutical particle engineering via spray drying. Pharm Res 25:999–1022
Yun SI, Attard D, Lo V, Davis J, Li H, Latella B, Tsvetkov F, Noorman H, Moricca S, Knott R, Hanley H, Morcom M, Simon GP, Gadd GEJ (2008) Spray-dried microspheres as a route to clay/polymer nanocomposites. Appl Polym Sci 108:1550–1556
Lee YD, Lee KS, Lee YH, Ju BK (2007) Field emission properties of carbon nanotube film using a spray method. Appl Surf Sci 254:513–516
Geng HZ, Kim KK, So KP, Lee YS, Chang Y, Lee YHJ (2007) Effect of acid treatment on carbon nanotube-based flexible transparent conducting films. Am Chem Soc 129:7758–7759
Foster LJR, Russell RA, Sanguanchaipaiwong V, Stone DJM, Hook JM, Holden PJ (2006) Biosynthesis and characterisation of deuterated polyhydroxyoctanoate (PHO). Biomacromolecules 7:1344–1349
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Yun, S.I., Lo, V., Noorman, J. et al. Morphology of composite particles of single wall carbon nanotubes/biodegradable polyhydroxyalkanoates prepared by spray drying. Polym. Bull. 64, 99–106 (2010). https://doi.org/10.1007/s00289-009-0173-5
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DOI: https://doi.org/10.1007/s00289-009-0173-5