Abstract
This paper summarizes a recent work on anti-corrosive and enhanced heat transfer properties of carboxylated water based nanofluids. DI water mixed with Sebacic acid (C10H18O4) as carboxylate additive is dispersed with multi walled carbon nanotubes and tested for corrosion and heat transfer characteristics. Corrosion studies made as per ASTM D 1384 show that carboxylate water dispersed with MWCNTs is resistant to corrosion and hence suitable for automotive environment. In addition to MWCNTs, carboxylated water dispersed with nano sized silver, copper and Aluminium oxide are also tested for corrosion performance but found to be giving considerable corrosion in automotive environment. The stability of MWCNT based nanofluids in terms of zeta potential is found to be good with carboxylated water compared to DI water. Significant improvement is observed in the thermal conductivity of nanofluids dispersed with MWCNTs. There is a slight increase in viscosity and marginal decrease in the specific heat of nanofluids with addition of carboxylate as well as MWCNTs. The carboxylated water is dispersed with very low mass concentration of multi walled carbon nano tubes at 0.025, 0.05 and 0.1 % and tested for heat transfer performance. The heat transfer studies are made in Reynolds number range of 2500–6000 in the developing flow regime. The heat transfer performance of nanofluids is carried out on an air cooled heat exchanger similar to an automotive radiator with incoming air velocities across radiator maintained at 5, 10 and 15 m/s. The coolant side overall heat transfer coefficient and overall heat transfer coefficient have improved markedly. It is also found that the velocity of air and flow rate of coolant plays an important role in enhancement of overall heat transfer coefficient. Stanton number correlation for the entire data has been developed. It is found that the wall temperature gradients play an important role in the enhancement of heat transfer when nanofluids are used.
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Abbreviations
- A:
-
Heat transfer area (m2)
- Cp :
-
Specific heat (kJ/kg K)
- D:
-
Diameter of the tube (m)
- hi :
-
Heat transfer coefficient (W/m2 K)
- k:
-
Thermal conductivity (W/m K)
- \({\dot{\text{m}}}\) :
-
Mass flow rate (kg/s)
- Re:
-
Reynolds number (\(\frac{{4\dot{m}}}{{\pi \mu D_{i} }}\))
- Q:
-
Heat transfer rate (W)
- Nu:
-
Nusselt number (\(\frac{{h_{i} D_{i} }}{{k_{l} }}\))
- P:
-
Pressure (Bar)
- Pr:
-
Prandtl number (\(\frac{{\mu_{l} c_{pl} }}{{k_{l} }}\))
- St:
-
Stanton number (\(\frac{Nu}{Re \cdot Pr}\))
- TC1 :
-
Temperature at inlet of air to radiator (°C)
- TC2 :
-
Temperature of air at outlet of air (°C)
- TH1 :
-
Temperature of water at inlet of radiator (°C)
- TH2 :
-
Temperature at outlet of radiator (°C)
- TB :
-
Bulk mean temperature (°C)
- TW :
-
Wall temperature (°C)
- ΔT:
-
Temperature difference
- U:
-
Overall heat transfer coefficient (W/m2 K)
- 1:
-
Inlet
- 2:
-
Outlet
- i:
-
Inside
- l:
-
Liquid
- lm:
-
Logarithmic mean
- nf:
-
Nanofluid
- o:
-
Outside
- th:
-
Theoretical
- Exp:
-
Experimental
- w:
-
Wall temperature
- ϕ:
-
Mass fraction of nano materials
- μ:
-
Dynamic viscosity (cP or kg/m s)
References
Chen XH, Chen CS, Chen Q, Cheng FQ, Zhang G, Chen ZZ (2002) Non-destructive purification of multi-walled carbon nanotube produced by catalyzed CVD. Mater Lett 57(3):734–738
Choi SUS (1995) Enhancing thermal conductivity of fluids with nanoparticles, developments and applications of non-newtonian flows. ASME 231:99–105
Choi SUS, Zhang ZG, Yu W, Lockwood FE, Grulke EA (2001) Anomalous thermal conductivity enhancement in nanotube suspensions. Appl Phys Lett 79:2252–2254
Das SK, Putra N, Thiesen P, Roetzel W (2003) Temperature dependence of thermal conductivity enhancement for nanofluids. ASME Trans J Heat Transf 125(4):567–574
Das SK, Choi SUS, Patel HE (2006) Heat transfer in nanofluids—a review. Heat Transf Eng 27(10):3–19
Ding Y, Alias H, Wen D, Williams RA (2006) Heat transfer of aqueous of carbon nanotubes (CNT nanofluids). Int J Heat Mass Transf 49(1–2):240–250
Hou PX, Bai S, Yang QH, Liu C, Cheng HM (2002) Multi-step purification of carbon nanotubes. Carbon 40(1):81–85
Patel HE, Sundararajan T, Das SK (2010) An experimental investigation into the thermal conductivity enhancement in oxide and metallic nanofluids. J Nanoparticle Res 12(3):1015–1031
Rosca ID, Watari F, Uo M, Akasaka T (2005) Oxidation of multiwalled carbon nanotubes by nitric acid. Carbon 43(15):3124–3131
Keblinski P, Eastman JA, Cahill DG (2005) Nanofluids for thermal transport. Mater Today 8(6):36–44
Lee S, Choi SUS, Li S, Eastman JA (1999) Measuring thermal conductivity of fluids containing oxide nanoparticles. J Heat Transf 121(2):280–289
Vaisman L, Wagner HD, Marom G (2006) The role of surfactants in dispersion of carbon nanotubes. Adv Colloid Interface Sci 128–130:37–46
Prasher R, Evans W, Meakin P, Fish J, Phelan P, Keblinski P (2006) Effect of aggregation on thermal conduction in colloidal nanofluids. Appl Phys Lett 89:143119
Teng T-P, Yu C-C (2013) Heat dissipation performance of MWCNTs nano-coolant for vehicle. Exp Thermal Fluid Sci 49:22–30
Chougule SS, Sahu SK (2014) Thermal performance of automobile radiator using carbon nanotube-water nanofluid—experimental study. J Therm Sci Eng Appl 6(4):041009
Wen D, Ding Y (2004) Experimental investigation into convective heat transfer of nanofluids at the entrance region under laminar flow conditions. Int J Heat Mass Transf 47(24):5181–5188
Chougule SS, Sahu SK (2014) Comparative study of cooling performance of automobile radiator using al2o3-water and carbon nanotube-water nanofluid. J Nanotechnol Eng Med 5:011001-1–011001-5
Wang X-Q, Mujumdar AS (2007) Heat transfer characteristics of nanofluids: a review. Int J Therm Sci 46(1):1–19
Xuan Y, Li Q (2003) Investigation on convective heat transfer and flow features of nanofluids. J Heat Transf 125(1):151–155
Xue CH, Zhou RJ, Shi MM, Gao Y, Wu G, Zhang XB et al (2008) The preparation of highly water-soluble multi-walled carbon nanotubes by irreversible noncovalent functionalization with a pyrene-carrying polymer. Nanotechnology 19(21):5604
Chiang Y-C, Lin W-H, Chang Y-C (2011) The influence of treatment duration on multi-walled carbon nanotubes functionalized by H2SO4/HNO3 oxidation. Appl Surf Sci 257(6):2401–2410
Acknowledgments
The authors gratefully acknowledge the financial assistance received from Hindustan Petroleum Corporation Ltd., for conducting the tests on the heat exchanger at GITAM University.
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Srinivas, V., Moorthy, C.V.K.N.S.N., Dedeepya, V. et al. Nanofluids with CNTs for automotive applications. Heat Mass Transfer 52, 701–712 (2016). https://doi.org/10.1007/s00231-015-1588-1
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DOI: https://doi.org/10.1007/s00231-015-1588-1