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Chemical characteristics of squeezable sap of hydrothermally treated silver birch logs (Betula pendula): effect of treatment time and the quality of the soaking water in pilot scale experiment

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Abstract

Little is currently known about the chemical changes that birch logs undergo during soaking in the plywood process. In order to probe the chemical changes in the log during soaking, sap obtained by mechanical compression from the log was chemically analyzed after pilot scale soaking at 70 °C. The results from the experiments revealed that the physical interaction between the core part of the log and the soaking water is limited. It was also suggested a water extraction causing significant increases in free monosaccharides and organic carbon concentrations in the sap. Assessment of the soaking water in the tank after soaking showed that the level of organic loading in water increases as the soaking temperature increases, probably due to the elution of organic substances from the bark. The dominant-free monosaccharides were glucose and fructose. Xylose and galactose also emerged during soaking. From the results, it is suspected that the majority of organic loadings in the water after soaking originate from the bark. This methodology for the sap collection seemed a reasonable approach to analyze the chemical characteristics of the xylem part of a log. Another aspect, relating to the seasonal variation of these changes in birch logs, is briefly discussed.

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References

  • Ahtonen S, Kallio H (1989) Identification and seasonal-variations of amino-acids in birch sap used for syrup production. Food Chem 33:125–132

    Article  CAS  Google Scholar 

  • Alén R (2000) Structure and chemical composition of wood. In: Stenius P (ed) Forest products chemistry. The Finnish Paper Engineer’s Association and Tappi, Helsinki, pp 11–57

    Google Scholar 

  • American Public Health Association (APHA) (2005) Standard methods for the examination of water and wastewater. American Public Health Association, Washington

    Google Scholar 

  • Datacenter Team (2014) Temperature records by month in Otaniemi area, Espoo, Finland. In: Aalto IT, Infrastructure services, Aalto University, Finland. http://outside.aalto.fi. Accessed Nov 2010

  • Duan Z, Sun R (2003) An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar. Chem Geol 193:257–271

    Article  CAS  Google Scholar 

  • Dundar T, As N, Korkut S, Unsal O (2008) The effect of boiling time on the surface roughness of rotary-cut veneers from oriental beech (Fagus orientalis L.). J Mater Process Technol 199:119–123

    Article  CAS  Google Scholar 

  • Eklund L (1990) Endogenous levels of oxygen, carbon dioxide and ethylene in stems of Norway spruce trees during one growing season. Trees 4:150–154

    Article  Google Scholar 

  • He LF, Terashima N (1990) Formation and structure of lignin in monocotyledons. 3. Heterogeneity of sugarcane (Saccharum officinarum L) lignin with respect to the composition of structural units in different morphological regions. J Wood Chem Technol 10:435–459

    Article  CAS  Google Scholar 

  • Jokela P, Keskitalo P (1999) Plywood mill water system closure by dissolved air flotation treatment. Water Sci Technol 40:33–41

    Article  CAS  Google Scholar 

  • Kallio H, Ahtonen S (1987) Seasonal-variations of the sugars in birch sap. Food Chem 25:293–304

    Article  CAS  Google Scholar 

  • Kılıç M, Hiziroglu S, Güllü C, Sezgin Z (2008) Influence of steaming on surface roughness of beech and sapele flooring material. J Mater Process Technol 199:448–451

    Article  Google Scholar 

  • Kovac-Besovic EE, Duric K, Kalodera Z, Sofic E (2009) Identification and isolation of pharmacologically active triterpenes in Betuale cortex, Betula pendula Roth., Betulaceae. Bosn J Basic Med Sci 9:31–38

    Google Scholar 

  • Krasutsky PA (2006) Birch bark research and development. Nat Prod Rep 23:919–942

    Article  CAS  PubMed  Google Scholar 

  • Kurth EF (1947) The chemical composition of barks. Chem Rev 40:33–49

    Article  CAS  PubMed  Google Scholar 

  • Lähdetie A, Liitiä T, Tamminen T, Pere J, Jääskeläinen A (2009) Activation of thermomechanical pulp by laccases as studied by UV–Vis, UV resonance Raman and FTIR spectroscopy 10(th) EWLP, Stockholm, Sweden, August 25–28, 2008. Holzforschung 63:745–750

    Article  Google Scholar 

  • Levey D, Bissell H, O’Keefe S (2000) Conversion of nitrogen to protein and amino acids in wild fruits. J Chem Ecol 26:1749–1763

    Article  CAS  Google Scholar 

  • Mäkinen R (2008) Drinking water quality and network materials in Finland summary report. Publications of Finnish Institute of Drinking Water 5. http://www.samk.fi/download/27214_Summary.pdf. Accessed May 2014

  • Marchand P, Chabot B (1978) Winter water relations of tree-line plant species on Mt-Washington, New-Hampshire. Arct Alp Res 10:105–116

    Article  Google Scholar 

  • Mayer I, Koch G (2007) Element content and pH value in American black cherry (Prunus serotina) with regard to colour changes during heartwood formation and hot water treatment. Wood Sci Technol 41:537–547

    Article  CAS  Google Scholar 

  • Mayer I, Koch G, Puls J (2007) Chemical investigations on boiling process waters in face veneer production. Holz Roh Werkst 65:315–320

    Article  CAS  Google Scholar 

  • McDonald AG, Fernandez M, Kreber B, Laytner F (2000) The chemical nature of kiln brown stain in radiata pine. Holzforschung 54:12–22

    Article  CAS  Google Scholar 

  • McGuire MA (2009) Carbon dioxide in xylem of trees: sources and fates. Dissertation, The Graduate Faculty of The University of Georgia, Athens

  • Ozarska B (2003) A manual decorative veneering technology. In: The Timber Veneer Association of Australia. Australian Government Forest & Wood Products Research and Development Corporation. http://www.timberveneer.asn.au/downloads/woodveneer_manual.pdf. Accessed May 2012

  • Robards K, Prenzler PD, Tucker G, Swatsitang P, Glover W (1999) Phenolic compounds and their role in oxidative processes in fruits. Food Chem 66:401–436

    Article  CAS  Google Scholar 

  • Rohumaa A, Antikainen T, Hughes M, Ohlmeyer M (2007) Process factors influencing birch (Betula pendula Roth) veneer surface properties and bond strength development in veneer-based products. In: Proceedings of the third international symposium on veneer processing and products, Shanghai, China, pp 131–139

  • Rohumaa A, Hughes M, Ohlmeyer M (2008) Factors influencing the properties of veneer-based products. In: Proceedings of the international panel products symposium, Espoo, Finland, pp 57–65

  • Rohumaa A, Hunt CG, Frihart CR, Saranpää P, Ohlmeyer M, Hughes M (2014) The influence of felling season and log-soaking temperature on the wetting and phenol formaldehyde adhesive bonding characteristics of birch veneer. Holzforschung. doi:10.1515/hf-2013-0166

    Google Scholar 

  • Schurr U (1998) Xylem sap sampling—new approaches to an old topic. Trends Plant Sci 3:293–298

    Article  Google Scholar 

  • Sellers T (1985) Definition and history of veneer and plywood. In: Sellers T (ed) Plywood and adhesive technology. Marcel Dekker Inc, New York, pp 1–3

  • Sixta H (2006) Multistage kraft pulping. In: Sixta H (ed) Handbook of Pulp, 1st edn. Wiley-VCH, Weinheim, pp 325–365

    Chapter  Google Scholar 

  • Sluiter A, Hames B, Ruiz R, Scarlata C, Sluiter J, Templeton D (2006) Determination of sugars, byproducts, and degradation products in liquid fraction process samples. National Renewable Energy Laboratory. http://www.nrel.gov/docs/gen/fy08/42623.pdf. Accessed 26 June 2014

  • Stockfors J, Linder S (1998) Effect of nitrogen on the seasonal course of growth and maintenance respiration in stems of Norway spruce trees. Tree Physiol 18:155–166

    Article  PubMed  Google Scholar 

  • Sundqvist B (2002) Color response of Scots pine (Pinus sylvestris), Norway spruce (Picea abies) and birch (Betula pubescens) subjected to heat treatment in capillary phase. Holz Roh Werkst 60:106–114

    Article  Google Scholar 

  • Sundqvist B, Morén T (2002) The influence of wood polymers and extractives on wood colour induced by hydrothermal treatment. Holz Roh Werkst 60:375–376

    Article  CAS  Google Scholar 

  • Testova L, Vilonen K, Pynnönen H, Tenkanen M, Sixta H (2009) Isolation of hemicelluloses from birch wood: distribution of wood components and preliminary trials in dehydration of hemicelluloses. Lenzing Ber 87:58–65

    CAS  Google Scholar 

  • Tyree MT (2001) Capillarity and sap ascent in a resurrection plant: does theory fit the facts? New Phytol 150:9–11

    Article  Google Scholar 

  • Yamamoto A, Rohumaa A, Kontturi E, Hughes M, Saranpää P, Andberg M, Vuorinen T (2013) Colorimetric behavior and seasonal characteristic of xylem sap obtained by mechanical compression from silver birch (Betula pendula). ACS Sustain Chem Eng 1:1075–1082

    Article  CAS  Google Scholar 

  • Yoruk R, Marshall M (2003) Physicochemical properties and function of plant polyphenol oxidase: a review. J Food Biochem 27:361–422

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This research was funded by Tekes (The Finnish Funding Agency for Technology and Innovation), UPM-Kymmene Wood Oy, Tikkurila Oyj, Stora Enso Timber Oy and Dynea Chemicals Oy.

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Correspondence to Eero Kontturi.

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Yamamoto, A., Rohumaa, A., Kontturi, E. et al. Chemical characteristics of squeezable sap of hydrothermally treated silver birch logs (Betula pendula): effect of treatment time and the quality of the soaking water in pilot scale experiment. Wood Sci Technol 49, 289–302 (2015). https://doi.org/10.1007/s00226-014-0693-5

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