Abstract
Although cocoa butter (CB) is an ideal fat for the use in chocolate, limited supply, high demand and fluctuating prices lead the industry to look for alternatives. In the present study, physicochemical properties of commercially available cocoa butter equivalents (CBE) and hard palm mid fraction (PMF) are compared with those of CB. Subsequently, their functionality in real and compound chocolate was evaluated. CBE and PMF contained a comparable (12.0–13.8 %) but significant lower amount of POSt compared to CB (38.7 %). Differences in nonisothermal crystallization and melting profile were observed between CB and CBE. The two-step isothermal crystallization at 20 °C showed that the nucleation started earlier as the StOSt content increased. No significant differences were observed in melting behavior between the reference chocolate (ChocREF) and the chocolates with partial replacement. Hardness was significantly higher for ChocREF. Differences in flow behavior were demonstrated in yield stress, but plastic viscosity of all chocolate products was similar. Although instrumental analyses defined differences, the trained panel and consumers had difficulties to distinguish the chocolate products produced from CBE.
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References
Smith KW (2001) Cocoa butter and cocoa butter equivalents. In: Gunstone F, Dekker M (eds) Structured lipids and modified lipids. CRC Press, New York, pp 401–422
Norberg S (2006) Chocolate and confectionery fats. In: Gunstone FD (ed) Modifying lipids for use in food. Woodhead Publishing, Cambridge, pp 488–516
Afoakwa EO, Paterson A, Fowler M, Vieira J (2008) Effects of tempering and fat crystallisation behaviour on microstructure, mechanical properties and appearance in dark chocolate systems. J Food Eng 89(2):128–136. doi:10.1016/j.jfoodeng.2008.04.021
Talbot G (2009) Vegetable fats. In: Beckett ST (ed) Industrial chocolate manufacture and use. Wiley-Blackwell, Oxford, pp 415–433. doi:10.1002/9781444301588.ch19
Van Malssen K, Peschar R, Schenk H (1996) Real-time X-ray powder diffraction investigations on cocoa butter. II. The relationship between melting behavior and composition of β-cocoa butter. J Am Oil Chem Soc 73(10):1217–1223. doi:10.1007/bf02525449
Verstringe S, De Clercq N, Nguyen MT, Kadivar S, Dewettinck K (2012) Enzymatic and other modification techniques to produce cocoa butter alternatives. In: Garti N, Widlak N (eds) Cocoa butter and related compounds. AOCS Press, Champaign, pp 443–474
Union E (2000) Directive 2000/36/EC of the European Parliament and of the Council relating to cocoa and chocolate products intended for human consumption:19–25
Foubert I, Dewettinck K, Janssen G, Vanrolleghem PA (2006) Modelling two-step isothermal fat crystallization. J Food Eng 75(4):551–559. doi:10.1016/j.jfoodeng.2005.04.038
Foubert I, Fredrick E, Vereecken J, Sichien M, Dewettinck K (2008) Stop-and-return DSC method to study fat crystallization. Thermochim Acta 471(1–2):7–13
Meilgaard MC, Carr BT, Civille GV (2006) Sensory evaluation techniques, 4th edn. Taylor & Francis, Boca Raton
Beckett ST (2003) Book review: confectionery fats handbook—properties, production and application by Ralph E. Timms. Eur J Lipid Sci Technol 105(9):557. doi:10.1002/ejlt.200390096
Padley FB, Paulussen CN, Soeters C, Tresser D (1981) Chocolate having defined hard fat. Google Patents
Lipp M, Simoneau C, Ulberth F, Anklam E, Crews C, Brereton P, de Greyt W, Schwack W, Wiedmaier C (2001) Composition of genuine cocoa butter and cocoa butter equivalents. J Food Compos Anal 14(4):399–408. doi:10.1006/jfca.2000.0984
Smith KW, Bhaggan K, Talbot G, Malssen KF (2011) Crystallization of fats: influence of minor components and additives. J Am Oil Chem Soc 88(8):1085–1101. doi:10.1007/s11746-011-1819-7
Timms RE (2003) Confectionery fats handbook: properties, production and application. Oily Press, Bridgwater
Cebula D, Smith K (1992) Differential scanning calorimetry of confectionery fats: part II—effects of blends and minor components. J Am Oil Chem Soc 69(10):992–998
Torbica A, Jovanovic O, Pajin B (2006) The advantages of solid fat content determination in cocoa butter and cocoa butter equivalents by the Karlshamns method. Eur Food Res Technol 222(3–4):385–391. doi:10.1007/s00217-005-0118-7
Dewettinck K, Foubert I, Basiura M, Goderis B (2004) Phase behavior of cocoa butter in a two-step isothermal crystallization. Cryst Growth Des 4(6):1295–1302. doi:10.1021/cg049772n
Foubert I, Vanrolleghem PA, Thas O, Dewettinck K (2004) Influence of chemical composition on the isothermal cocoa butter crystallization. J Food Sci 69(9):E478–E487
Szczesniak AS (2002) Texture is a sensory property. Food Qual Prefer 13(4):215–225. doi:10.1016/S0950-3293(01)00039-8
Vítová E, Loupancová B, Štoudková H, Macků I, Zemanová J, Babák L (2009) Effect of fat composition on some physico-chemical parameters and sensorial evaluation of dark chocolate. J Food Nutr Res 48(2):72–79
Beckett ST (ed) (2009) Chocolate flow properties. In: Industrial chocolate manufacture and use, 4th edn. Wiley-Blackwell, Oxford, UK. doi:10.1002/9781444301588.ch10
Maheshwari B, Yella Reddy S (2005) Application of kokum (Garcinia indica) fat as cocoa butter improver in chocolate. J Sci Food Agric 85(1):135–140. doi:10.1002/jsfa.1967
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De Clercq, N., Kadivar, S., Van de Walle, D. et al. Functionality of cocoa butter equivalents in chocolate products. Eur Food Res Technol 243, 309–321 (2017). https://doi.org/10.1007/s00217-016-2745-6
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DOI: https://doi.org/10.1007/s00217-016-2745-6