Fresenius' Journal of Analytical Chemistry

, Volume 365, Issue 5, pp 404–408

Saturation effects in the laser ablation of stainless steel in air at atmospheric pressure

  • L. M. Cabalín
  • D. Romero
  • J. M. Baena
  • J. J. Laserna
Original paper

DOI: 10.1007/s002160051631

Cite this article as:
Cabalín, L., Romero, D., Baena, J. et al. Fresenius J Anal Chem (1999) 365: 404. doi:10.1007/s002160051631

Abstract

A pulsed Nd : YAG laser was used to generate a plasma from stainless steel targets in air at atmospheric pressure. Laser focusing was found to be an important factor in the ablation process. The influence of focal conditions on spatial profiles of plasma, emission intensity and averaged ablation rate (AAR, μm pulse–1) of stainless steel samples as a function of laser energy are discussed. At high energies and depending on laser beam focusing, ablation efficiency tends to decrease compared to that at lower energies. This effect can be due to plasma shielding and air breakdown. The averaged ablation rate was found to be dependent on the thickness of the sample. This effect results in shielding of the incoming laser beam and redeposition of removed material in the crater. By focusing the beam inside the material free expansion of plasma is allowed, resulting in more efficient erosion of the sample at larger energies. For comparative purposes, data on ablated mass per pulse are presented.

Copyright information

© Springer-Verlag Berlin Heidelberg 1999

Authors and Affiliations

  • L. M. Cabalín
    • 1
  • D. Romero
    • 1
  • J. M. Baena
    • 2
  • J. J. Laserna
    • 1
  1. 1.Department of Analytical Chemistry, Faculty of Sciences, University of Málaga, E-29071 Málaga, Spain e-mail: laserna@uma.esES
  2. 2.Acerinox, S. A., E-11379 Los Barrios (Cádiz), SpainES