Abstract
A single collector double focusing sector field ICP-MS is evaluated for the determination of isotope ratios. Spectral interferences (e.g. 40Ar23Na on 63Cu) can lead to calculation of inaccurate ratios. The use of high resolution enables such interferences to be separated from the isotopes of interest. External reproducibilities of < 0.02% are shown for uninterfered isotopes (measured at low resolution R = 300) and < 0.1% for interfered isotopes which required the use of medium (R = 4000) and high resolution (R = 10000).
Similar content being viewed by others
Author information
Authors and Affiliations
Additional information
Received: 11 January 1999 / Revised: 8 April 1999 / Accepted: 11 April 1999
Rights and permissions
About this article
Cite this article
Hamester, M., Wiederin, D., Wills, J. et al. Strategies for isotope ratio measurements with a double focusing sector field ICP-MS. Fresenius J Anal Chem 364, 495–498 (1999). https://doi.org/10.1007/s002160051374
Issue Date:
DOI: https://doi.org/10.1007/s002160051374