Abstract
For the past 25 years the National Institute of Standards and Technology (NIST) has developed certified reference materials (CRMs), known as standard reference materials (SRMs), for determination of organic contaminants in environmental matrices. Assignment of certified concentrations has usually been based on combining results from two or more independent analytical methods. The first-generation environmental-matrix SRMs were issued with certified concentrations for a limited number (5 to 10) of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs). Improvements in the analytical certification approach significantly expanded the number and classes of contaminants determined. Environmental-matrix SRMs currently available include air and diesel particulate matter, coal tar, marine and river sediment, mussel tissue, fish oil and tissue, and human serum, with concentrations typically assigned for 50 to 90 organic contaminants, for example PAHs, nitro-substituted PAHs, PCBs, chlorinated pesticides, and polybrominated diphenyl ethers (PBDEs).
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Acknowledgments
The following members and former members of the Analytical Chemistry Division are acknowledged for their participation in the preparation and certification of the SRMs described in this review: H.A. Bamford, B.A. Benner, Jr., D.Z. Bezabeh, W.W. Brubaker Jr., S.N. Chesler, M.J. Hays, M. Lopez de Alda, S.M. Mössner, R.M. Parris, A.M. Peck, R.S. Pugh, B.J. Porter, R.E. Rebbert, K.E. Sharpless, H.M. Stapleton, and P. Schubert. We also thank S. Leigh of the NIST Statistical Engineering Division for statistical consultation and analysis of the results as part of the value assignment process for the recent SRMs. We also acknowledge the following members of the NIST Standard Reference Materials Program for coordination of the support aspects involved in the preparation and issuance of recent SRMs: M.P. Cronise, C.N. Fales, B.S. MacDonald, and R.L. Watters Jr.
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Commercial equipment or materials are identified in this paper to specify adequately the experimental procedure. Such identification does not imply recommendation or endorsement by NIST, nor does it imply that the materials or equipment identified are necessarily the best available for the purpose.
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Wise, S.A., Poster, D.L., Kucklick, J.R. et al. Standard reference materials (SRMs) for determination of organic contaminants in environmental samples. Anal Bioanal Chem 386, 1153–1190 (2006). https://doi.org/10.1007/s00216-006-0719-4
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DOI: https://doi.org/10.1007/s00216-006-0719-4