Abstract
The impact of pollutants from road runoff on receiving water bodies becomes increasingly serious. However, less is known about the study on the distribution of metal speciation in particles with different sizes, and the interaction among metal speciation. Our research is aimed at investigating speciation distribution of copper (Cu) and zinc (Zn) in particles and the interaction among metal speciation. Stainless steel sieves in different sizes were used to accomplish filtration scheme. Sequential extraction procedures contained five steps for the chemical fractionation of metals. Flame atomic absorption spectrometry (Shimadzu, AA-6800) was used to determine the concentration of metal speciation. Speciation distribution of Cu was similar to that of Zn. Size distribution implied that small particles (<75 μm) determined the distribution for both Cu and Zn, as well as their migration. Correlation analysis indicated that the interaction among speciation of Cu was different from that of Zn.
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Bibby RL, Webster-Brown JG (2006) Trace metal adsorption onto urban stream suspended particulate matter (Auckland region, New Zealand). Appl Geochem 21:1135–1151
Camponelli KM, Lev SM, Snodgrass JW, Landa ER, Casey RE (2010) Chemical fractionation of Cu and Zn in stormwater, roadway dust and stormwater pond sediments. Environ Pollut 158:2143–2149
Cortecci G, Boschetti T, Dinelli E, Cidu R, Podda F, Doveri M (2009) Geochemistry of trace elements in surface waters of the Arno River Basin, northern Tuscany, Italy. Appl Geochem 24:1005–1022
Davis B, Birch G (2010) Comparison of heavy metal loads in stormwater runoff from major and minor urban roads using pollutant yield rating curves. Environ Pollut 158:2541–2545
Dean CM, Sansalone JJ, Cartledge FK, Pardue JH (2005) Influence of hydrology on rainfall-runoff metal element speciation. J Environ Eng-ASCE 131:632–642
Dong A, Chesters G, Simsiman GV (1984) Metal composition of soil, sediments and urban dust and dirt samples from the Menomonee River watershed, Wisconsin, USA. Water Air Soil Poll 22:257–275
Eaton AD, Clesceri LS, Greenberg AE (1999) Standard methods for the examination of water and wastewater, 20th edn. American public health association, American public health association, Washington
Herngren L, Goonetilleke A, Ayoko GA (2005) Understanding heavy metal and suspended solids relationships in urban stormwater using simulated rainfall. J Environ Manage 76:149–158
Janssen CR, Heijerick DG, De Schamphelaere KAC, Allen HE (2003) Environmental risk assessment of metals: tool for incorporating bioavailability. Environ Int 28:793–800
Kayhanian M, Suverkropp C, Ruby A, Tsay K (2007) Characterization and prediction of highway runoff constituent event mean concentration. J Environ Manage 85:279–295
Kayhanian M, Stransky C, Bay S, Lau SL, Stenstrom MK (2008) Toxicity of urban highway runoff with respect to storm duration. Sci Total Environ 389:386–406
Kim JY, Sansalone JJ (2008) Event-based size distributions of particulate matter transported during urban rainfall-runoff events. Water Res 42:2756–2768
Lee P-K, Yu Y-H, Yun S-T, Mayer B (2005) Metal contamination and solid phase partitioning of metals in urban roadside sediments. Chemosphere 60:672–689
Li H, Shi JQ, Shen G, Ji XL, Fu DF (2009a) Characteristics of metals pollution in expressway stormwater runoff. Environ Sci 30:1621–1625 (In Chinese)
Li LY, Hall K, Yi Y, Mattu G, McCallum D, Min C (2009b) Mobility and bioavailability of trace metals in the water-sediment system of the highly urbanized brunette watershed. Water Air Soil Poll 197:249–266
Mangani G, Berloni A, Bellucci F, Tatano F, Maione M (2005) Evaluation of the pollutant content in road runoff first flush waters. Water Air Soil Poll 160:213–228
MEPC (2002) Environmental quality standards for surface water (GB3838). Beijing, China: ministry of environmental protection of the people’s republic of China. (in Chinese)
Murakami M, Sato N, Anegawa A, Nakada N, Harada A, Komatsu T et al (2008) Multiple evaluations of the removal of pollutants in road runoff by soil infiltration. Water Res 42:2745–2755
Murakami M, Fujita M, Furumai H, Kasuga I, Kurisu F (2009) Sorption behavior of heavy metal species by soakaway sediment receiving urban road runoff from residential and heavily trafficked areas. J Hazard Mater 164:707–712
Pettersson TJR (1998) Water quality improvement in a small stormwater detention pond. Water Sci Technol 38:115–122
Sansalone JJ, Buchberger SG (1997) Partitioning and first flush of metals in urban roadway storm water. J Environ Eng - ASCE 123:134–143
Sansalone JJ, Glenn DW III (2002) Accretion of pollutants in snow exposed to urban traffic and winter storm maintenance activities. J Environ Eng - ASCE 128:151–166
Smeda A, Zyrnicki W (2002) Application of sequential extraction and the ICP-AES method for study of the partitioning of metals in fly ashes. Microchem J 72(1):9
Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51:844–851
Tuccillo ME (2006) Size fractionation of metals in runoff from residential and highway storm sewers. Sci Total Environ 355:288–300
Us EPA (1983) Results of national urban runoff program. Water planning division, U. S. environmental protection Agency, Washington, DC
Yousef YA, Harper HH, Wiseman LP, Bateman JM (1985) Consequential species of heavy metals in highway runoff, Washington, D.C.: transportation research board. Transportion Research Record 1017:56–62
Zuo XJ, Singh RP, Fu DF, Li H (2011) Particle size distribution variation during highway runoff settling. Fresen Environ Bull 20:1020–1026
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This research was funded by A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), China.
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Li, H., Zuo, X.J. Speciation and Size Distribution of Copper and Zinc in Urban Road Runoff. Bull Environ Contam Toxicol 90, 471–476 (2013). https://doi.org/10.1007/s00128-012-0953-8
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DOI: https://doi.org/10.1007/s00128-012-0953-8