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Polymer Sol-Gel Synthesis of Hybrid Nanocomposites

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Abstract

The current state and main problems of polymer sol-gel synthesis as a method of the preparation of hybrid polymer-inorganic nanocomposites are analyzed. The general characterization of sol-gel reactions is given and the routes of the combination of sol-gel synthesis with the polymerization of traditional monomers are considered. Particular attention is given to the formation of sol-gel precursors in the presence of organic polymers, including the formation of interpenetrating hybrid networks. The specificity of hybrid nanocomposites based on multicomponent ceramics is discussed. The sol-gel process is analyzed as a promising route for the preparation of bioceramics in the presence of templates.

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REFERENCES

  1. Inorganic and Organometallic Polymers with Special Properties, Ed. by Laine, R.M., NATO ASI Ser., 1992, vol. 206.

  2. Sugimoto, T., Fine Particles. Synthesis, Characterization and Mechanism of Growth, New York: Marcel Dekker, 2000.

    Google Scholar 

  3. Yoshinaga, K., Bull. Chem. Soc. Jpn., 2002, vol. 75, p. 2349.

    Article  CAS  Google Scholar 

  4. McCarthy, D.W., Mark, J.E., and Schaefer, D.W., J. Polym. Sci., Part B: Polym. Phys., 1998, vol. 36, p. 1167.

    CAS  Google Scholar 

  5. Hybrid Organic-Inorganic Composites, Ed. by Mark, J.E., Lee, C.Y.-E., and Bianconi, P.A., Washington: American Chemical Society, 1995.

    Google Scholar 

  6. Pomogailo, A.D., Usp. Khim., 2000, vol. 69, p. 60.

    Google Scholar 

  7. Pomogailo, A.D., Vysokomol. Soedin. (in press).

  8. Wen, J. and Wilkes, G.L., in The Polymeric Materials Encyclopedia: Synthesis, Properties, and Applications, Boca Raton: CRC, 1995.

    Google Scholar 

  9. Chiola, V., Ritsko, J.E., and Vanderpool, C.D., US Patent 3 556 725, 1971.

  10. Day, V.W., Eberspacher, T.A., and Chen, Y., Inorg. Chim. Acta, 1995, vol. 229, p. 391.

    Article  CAS  Google Scholar 

  11. Shilova, O.A. and Shilov, V.V., in Nanosistemy, nanomaterialy, nanotekhnologii (Nanosystems, Nanomaterials, Nanotechnologies), Shpak, A.P., Ed., Kiev: Akademperiodika, 2003, vol. 1, p. 9.

    Google Scholar 

  12. Golubko, N.V., Yanovskaya, M.I., Prutchenko, S.G., and Obolonkova, E.S., Neorg. Mater., 1998, vol. 34, p. 1115.

    Google Scholar 

  13. Beecroft, L.L. and Ober, C.K., Adv. Mater. (Weinheim, Fed. Repub. Ger.), 1995, vol. 7, p. 1009.

    Article  CAS  Google Scholar 

  14. Nabai, M., Sanchez, C., and Livage, J., Eur. J. Solid State Inorg. Chem., 1988, vol. 28, p. 1173.

    Google Scholar 

  15. Inagaki, S., Guan, S., Fukushima, Y., et al., J. Am. Chem. Soc., 1999, vol. 121, p. 9611.

    Article  CAS  Google Scholar 

  16. Gunji, T., Sopyan, I., and Abe, Y., J. Polym. Sci., Part A: Polym. Chem., 1994, vol. 32, p. 3133.

    Article  CAS  Google Scholar 

  17. Smidt, H. and Seiferling, B., Mater. Res. Soc. Symp. Proc., 1986, vol. 73, p. 739.

    Google Scholar 

  18. Corma, A., Chem. Rev., 1997, vol. 97, p. 2373.

    Article  CAS  Google Scholar 

  19. Kovalenko, A.S., Korchev, A.S., Chernenko, J.V., et al., Adsorpt. Sci. Technol., 1999, vol. 17, p. 245.

    CAS  Google Scholar 

  20. Yao, B. and Zhang, L., J. Mater. Sci., 1999, vol. 34, p. 5983.

    Article  CAS  Google Scholar 

  21. Kakihana, M. and Yoshimura, M., Bull. Chem. Soc. Jpn., 1999, vol. 72, p. 1427.

    Article  CAS  Google Scholar 

  22. Sanchez, C. and Ribot, F., New J. Chem., 1994, vol. 18, p. 1007.

    CAS  Google Scholar 

  23. Que, W., Hu, X., and Zhang, Q.Y., Chem. Phys. Lett., 2003, vol. 369, p. 354.

    Article  CAS  Google Scholar 

  24. Pomogailo, A.D. and Savost'yanov, V.S., Synthesis and Polymerization of Metal-Containing Monomers, Boca Raton: CRC, 1994.

    Google Scholar 

  25. Camail, M., Humbert, M., Margaillan, A., et al., Polymer, 1998, vol. 39, p. 6525.

    CAS  ISI  Google Scholar 

  26. Igarashi, N., Tanaka, Y., Nakata, S., and Tatsumi, T., Chem. Lett., 1999, p. 1.

  27. Gross, S., Di Noto, V., Kickelbick, G., and Schubert, U., Mater. Res. Soc. Symp. Proc., 2002, vol. 726, p. Q4.1.1.

    Google Scholar 

  28. Hubert-Pfalzgraf, L.G., Abada, V., Halut, S., and Roziere, J., Polyhedron, 1997, vol. 16, p. 581.

    CAS  Google Scholar 

  29. Long, L. and Ruckenstein, E., J. Appl. Polym. Sci., 1998, vol. 67, p. 1891.

    Google Scholar 

  30. Moraru, B., Hussing, N., Kickelbick, G., et al., Chem. Mater., 2002, vol. 14, p. 2732.

    Article  CAS  Google Scholar 

  31. Trimmel, G., Gross, S., Kickelbick, G., and Schubert, U., Appl. Organomet. Chem., 2001, vol. 15, p. 401.

    Article  CAS  Google Scholar 

  32. Dzhardimalieva, G.I., Pomogailo, A.D., and Shupik, A.N., Izv. Akad. Nauk SSSR, Ser. Khim., 1985, no. 2, p. 451.

  33. Pomogailo, A.D. and Golubeva, N.D., Izv. Ross. Akad. Nauk, Ser. Khim., 1994, no. 12, p. 2139.

  34. Schubert, U., Schwertfeger, F., and Gorsmann, C., in Nanotechnology. Molecularly Designed Materials, Chow, G.-M. and Gonsalves, K.E., Eds., Washington, DC: American Chemical Society, 1996, p. 366.

    Google Scholar 

  35. Evans, W.J., Ansari, M.A., and Ziller, J.W., Inorg. Chem., 1999, vol. 38, p. 1160.

    CAS  Google Scholar 

  36. Dahmouche, K., Carlos, L.D., Santilli, C.V., et al., J. Phys. Chem., B, 2002, vol. 106, p. 4377.

    Article  CAS  Google Scholar 

  37. Valid, P., Tanski, M., Pette, M., et al., Inorg. Chem., 1999, vol. 38, p. 3394.

    Google Scholar 

  38. Yoshihara, M., Oie, H., Okada, A., et al., Macromolecules, 2002, vol. 35, p. 2435.

    Article  CAS  ISI  Google Scholar 

  39. Gao, F., Tong, Y., Schricker, S.R., and Culbertson, B.M., Polym. Adv. Technol., 2001, vol. 12, p. 355.

    CAS  Google Scholar 

  40. Tamaki, R., Naka, K., and Chujo, Y., Polym. J. (Tokyo), 1998, vol. 30, p. 60.

    Article  CAS  Google Scholar 

  41. Schubert, U., Husing, N., and Lorenz, A., Chem. Mater., 1995, vol. 7, p. 2010.

    Article  CAS  Google Scholar 

  42. Lee, A. and Lichtenhan, D., J. Appl. Polym. Sci., 1999, vol. 73, p. 1993.

    CAS  Google Scholar 

  43. Jacob, M.M.E., Hackett, E., and Giannelis, E.P., J. Mater. Chem., 2003, vol. 13, p. 1.

    CAS  Google Scholar 

  44. Kloster, G.M., Taylor, C.M., and Watton, S.P., Inorg. Chem., 1999, vol. 38, p. 3954.

    Article  CAS  Google Scholar 

  45. Hsiue, G.-H., Lee, R.-H., and Jeng, R.-J., Polymer, 1999, vol. 40, p. 6417.

    Article  CAS  ISI  Google Scholar 

  46. Camail, M., Hubert, M., Margaillan, A., and Vernet, J.L., Polymer, 1998, vol. 25, p. 6533.

    Google Scholar 

  47. Matyjaszewski, K. and Davis, T.P., Handbook of Radical Polymerization, Hoboken: Wiley, 2002.

    Google Scholar 

  48. Hong, S.C., Lutz, J.-F., Inoue, Y., et al., Macromolecules, 2003, vol. 36, p. 1075.

    CAS  ISI  Google Scholar 

  49. Pomogailo, A.D., Rozenberg, A.S., and Uflyand, I.E., Nanochastitsy metallov v polimerakh (Metal Nanoparticles in Polymers), Moscow: Khimiya, 2000.

    Google Scholar 

  50. Wallbank, A.I. and Corrigan, J.F., Can. J. Chem., 2002, vol. 80, p. 1592.

    Article  CAS  Google Scholar 

  51. Carroll, J.B., Waddon, A.J., Nakade, H., and Rotello, V.M., Macromolecules, 2003, vol. 36, p. 6289.

    Article  CAS  ISI  Google Scholar 

  52. Shiho, H. and Kawahashi, N., Colloid Polym. Sci., 2000, vol. 278, p. 270.

    Article  CAS  Google Scholar 

  53. Nakane, K., Ohashi, J., and Suzuki, F., J. Appl. Polym. Sci., 1999, vol. 71, p. 185.

    Article  CAS  Google Scholar 

  54. Sherman, M.A. and Kennedy, J.P., J. Polym. Sci., Part A: Polym. Chem., 1998, vol. 36, p. 1891.

    CAS  Google Scholar 

  55. Dzhardimalieva, G.I., Golubeva, N.D., Bochkin, A.M., et al., Abstracts of Papers, E-MRS 2003. Fall Meeting, Warsaw, 2003, p. 219.

  56. Juangvanich, N. and Mauritz, K.A., J. Appl. Polym. Sci., 1998, vol. 67, p. 1799.

    Article  CAS  Google Scholar 

  57. Zhou, W., Dong, J.H., Qiu, K.Y., and Wei, Y., J. Polym. Sci., Part A: Polym. Chem., 1998, vol. 36, p. 1607.

    CAS  Google Scholar 

  58. Zhang, J., Luo, S.C., and Gui, L.L., J. Mater. Sci., 1997, vol. 32, p. 1469.

    CAS  Google Scholar 

  59. Wei, Y., Jin, D., Wei, G., et al., J. Appl. Polym. Sci., 1998, vol. 70, p. 1689.

    CAS  Google Scholar 

  60. Tamaki, R. and Chujo, Y., Chem. Commun., 1998, p. 1131.

  61. De Paul, S.M., Zwanziger, J.W., Ulrich, R., et al., J. Am. Chem. Soc., 1999, vol. 121, p. 5727.

    Google Scholar 

  62. Bekiari, V., Lianos, P., and Judeinstein, P., Chem. Phys. Lett., 1999, vol. 307, p. 310.

    Article  CAS  Google Scholar 

  63. Kuraoka, K., Chujo, Y., and Yamazawa, T., Chem. Commun., 2000, p. 2477.

  64. Hu, Q. and Marand, E., Polymer, 1999, vol. 40, p. 4833.

    CAS  ISI  Google Scholar 

  65. Yoshida, M., Lal, M., Kumar, N.D., and Prasad, P.N., J. Mater. Sci., 1997, vol. 32, p. 4047.

    Article  CAS  Google Scholar 

  66. Hedrick, L., Cha, H.-J., Miller, R.D., et al., Macromolecules, 1997, vol. 30, p. 8512.

    CAS  ISI  Google Scholar 

  67. Pomogailo, A.D. and Kestelman, V.N., Metallopolymer Nanocomposites, Berlin: Springer, 2005.

    Google Scholar 

  68. Zheng, M.-P., Jin, Y.-P., Jin, G.-L., and Gu, M.-Y., J. Mater. Sci. Lett., 2000, vol. 19, p. 433.

    CAS  Google Scholar 

  69. Guo, H., Zhao, X., Ning, G., and Liu, G., Langmuir, 2003, vol. 19, no.12, p. 4884.

    Article  CAS  ISI  Google Scholar 

  70. Tang, J.-B., Qiu, K.-Y., and Wei, Y., Chin. J. Chem., 2001, vol. 19, p. 198.

    CAS  Google Scholar 

  71. Landry, C.J.T., Coltrain, B.K., Teegarden, D.M., et al., Macromolecules, 1996, vol. 29, p. 4712.

    Article  CAS  ISI  Google Scholar 

  72. Van Dover, R.B., Schneemeyer, L.F., and Fleming, R.M., Nature (London), 1998, vol. 392, p. 162.

    Google Scholar 

  73. Waada, K., Yamada, K., Kondo, T., and Mitsudo, T., Chem. Lett., 2001, p. 12.

  74. Liu, C., Zou, B., Rondinone, A.J., and Zhang, Z.J., J. Am. Chem. Soc., 2001, vol. 123, p. 4344.

    CAS  Google Scholar 

  75. Kakihana, M., Okubo, T., Nakamura, Y., et al., J. Sol-Gel Sci. Technol., 1998, vol. 12, p. 95.

    Article  CAS  Google Scholar 

  76. Zhang, W. and Pinnavaia, T.J., Catal. Lett., 1996, vol. 38, p. 261.

    CAS  Google Scholar 

  77. Kakihana, M., Okubo, T., Arima, M., et al., Chem. Mater., 1997, vol. 9, p. 451.

    Article  CAS  Google Scholar 

  78. Udawatte, C.P., Kakihana, M., and Yoshimura, M., Solid State Ionics, 1998, vol. 108, p. 23.

    Article  CAS  ISI  Google Scholar 

  79. O'Brien, S., Brus, L., and Murray, C.B., J. Am. Chem. Soc., 2001, vol. 123, p. 12 085.

    Article  Google Scholar 

  80. Schwartz, R.W., Chem. Mater., 1997, vol. 9, p. 2325.

    CAS  Google Scholar 

  81. Noda, K., Sakamoto, W., Kikuta, K., et al., Chem. Mater., 1997, vol. 9, p. 2174.

    Article  CAS  Google Scholar 

  82. Hagrman, D., Zubieta, C., and Rose, D.J., Angew. Chem., Int. Ed. Engl., 1997, vol. 36, p. 795.

    Article  Google Scholar 

  83. Martino, A., Sault, A.G., Kawola, J.S., et al., J. Catal., 1999, vol. 187, p. 30.

    Article  CAS  Google Scholar 

  84. Biochemical Aspects of Sol-Gel Science and Technology, Avnir, D. and Braun, S., Eds., Boston: Kluwer Academic, 1996.

    Google Scholar 

  85. Sarikaya, M., Tamerler, C.A., Jen, K.-Y., et al., Nature Mater., 2003, vol. 2, p. 577.

    Article  CAS  Google Scholar 

  86. Calvert, P. and Rieke, P., Chem. Mater., 1996, vol. 8, p. 1715.

    CAS  Google Scholar 

  87. The Biomineralization of Nano-and Microstructures, Bauerlein, E., Ed., Weinheim: Wiley-VCH, 2000.

    Google Scholar 

  88. Mirkin, C.A. and Taton, T.A., Nature (London), 2000, vol. 405, p. 626.

    Article  CAS  ISI  Google Scholar 

  89. Niemeyer, C.M., Angew. Chem., Int. Ed. Engl., 2001, vol. 40, p. 4128.

    CAS  Google Scholar 

  90. Brusentsov, N.A. and Brusentsova, T.N., Khim.-Farm. Zh., 2001, vol. 35, no.6, p. 10.

    Google Scholar 

  91. Medvedeva, S.A., Aleksandrova, G.P., Grishchenko, L.A., and Tyukavkina, N.A., Zh. Obshch. Khim., 2002, vol. 72, p. 1569.

    Google Scholar 

  92. Braun, S., Rappoport, S., Zusman, R., et al., Mater. Lett., 1990, vol. 10, p. 1.

    Article  CAS  Google Scholar 

  93. Dabbs, D.M. and Aksay, I.A., Annu. Rev. Phys. Chem., 2000, vol. 51, p. 601.

    Article  CAS  Google Scholar 

  94. Biomimetics, Starikaya, M. and Aksay, I.A., Eds., New York: AIP Press, 1995.

    Google Scholar 

  95. Brown, S., Sarikaya, M., and Johnson, E., J. Mol. Biol., 2000, vol. 299, p. 725.

    Article  CAS  Google Scholar 

  96. Goller, G., Demirkian, H., Oktar, F.N., and Demirkesen, E., Ceram. Int., 2003, vol. 29, p. 721.

    Article  CAS  Google Scholar 

  97. Mann, S., J. Chem. Soc., Dalton Trans., 1993, no. 1, p. 3953.

  98. Tsuru, K., Ohtsuki, C., Osaka, A., et al., J. Mater. Sci.: Mater. Med., 1997, vol. 8, p. 157.

    Article  CAS  Google Scholar 

  99. Klaus, T., Joerger, R., Olsson, E., and Granqist, S., Proc. Natl. Acad. Sci. USA, 1999, vol. 96, p. 13 611.

    Article  CAS  Google Scholar 

  100. Zink, J.I., Valentine, J.S., and Dunn, B., New J. Chem., 1994, vol. 18, p. 1109.

    CAS  Google Scholar 

  101. Protein Architecture: Interfacing Molecular Assemblies and Immobilization Biotechnology, Lvov, Y. and Mohwald, H., Eds., New York: Marcel Dekker, 2000.

    Google Scholar 

  102. Bronshtein, A., Aharonson, N., Avnir, D., et al., Chem. Mater., 1997, vol. 9, p. 2632.

    Article  CAS  Google Scholar 

  103. Roux, C., Livage, J., Farhati, K., and Monjour, L., J. Sol-Gel Sci. Technol., 1997, vol. 8, p. 663.

    Article  CAS  Google Scholar 

  104. Shabat, D., Grynszpan, F., Saphier, S., et al., Chem. Mater., 1997, vol. 9, p. 2258.

    Article  CAS  Google Scholar 

  105. Immobilized Cells and Enzymes: A Practical Approach, Woodward, J., Ed., Washington, DC: IRL Press, 1985.

    Google Scholar 

  106. Jain, T.K., Roy, I., De, T.K., and Maitra, A., J. Am. Chem. Soc., 1998, vol. 120, p. 11 092.

    CAS  Google Scholar 

  107. Geomicrobiology: Interactions between Microbes and Minerals, Banfield, J.F. and Nealson, K.H., Eds., Washington, DC: Mineralogical Society of America, 1997, vol. 35.

    Google Scholar 

  108. Stevens, N.S.M. and Rezac, M.E., Polymer, 1999, vol. 40, p. 4289.

    Article  CAS  ISI  Google Scholar 

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Translated from Kolloidnyi Zhurnal, Vol. 67, No. 6, 2005, pp. 726–747.

Original Russian Text Copyright © 2005 by Pomogailo.

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Pomogailo, A.D. Polymer Sol-Gel Synthesis of Hybrid Nanocomposites. Colloid J 67, 658–677 (2005). https://doi.org/10.1007/s10595-005-0148-7

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