Abstract
The variations in certain spin-Hamiltonian parameters of the Cu++ ion in dibarium copper formate tetrahydrate with temperature have been studied. Optical absorption investigations on single crystals of the salt at room temperature and 90° K. are reported. The results are discussed in terms of a model in which vibronic mixing of certain electron levels of the Cu++ ion play an important role.
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Ramasubba Reddy, T. and Srinivasan, R.Proc. Indian Acad. Sci., 1967,65, 303.
—————..Physics Letter, 1966,22, 143.
Bowers, K. D. and Owen, J.Reports Prog. Phys., 1955,18, 356.
Gerritson, H. J. and Sabisky, E. S.Phys. Rev., 1962,125, 1853.
Soubek, Z. and Zdansky, K.J. Chem. Phys., 1966,44, 3078.
Liehr, A. D. and Ballahausen, C. J.Phys. Rev., 1957,106, 1161.
Cotton, F. A...Chemical Applications of Group Theory. John Wiley and Sons, Inc., New York, 1963.
Englman, R...Mol. Phys., 1960,3, 23.
Owen, J...Proc. Roy. Soc., 1955,227 A, 153.
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Communicated by Prof. R. S. Krishnan,f.a.sc.
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Reddy, T.R., Srinivasan, R. ESR study of dibarium copper formate tetrahydrate. Proc. Indian Acad. Sci. 65, 368–375 (1967). https://doi.org/10.1007/BF03054099
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DOI: https://doi.org/10.1007/BF03054099