Proceedings of the Indian Academy of Sciences - Section A

, Volume 64, Issue 1, pp 36-43

First online:

Infra-red and raman spectra of BaCl2.2H2O and BaCl2.2D2O

  • G. M. VenkateshAffiliated withPhysics Department, Indian Institute of Science
  • , P. NeelakantanAffiliated withPhysics Department, Indian Institute of Science

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The infra-red and Raman spectra of ordinary and deuterated barium chloride dihydrate have been studied to throw light on the intramolecular hydrogen bonds in these two crystals. The frequencies of the stretching, bending and librational modes observed in infra-red and Raman spectra exclude the possibility of at least one of the OH.... Cl hydrogen bonds, contrary to the results of NMR and neutron diffraction studies.