Modern Trends In Inorganic Chemistry

Proceedings of the Indian Academy of Sciences - Chemical Sciences

, Volume 108, Issue 3, pp 111-121

First online:

New main group ligands for complexation with transition and inner transition elements

  • S S KrishnamurthyAffiliated withDepartment of Inorganic and Physical Chemistry, Indian Institute of Science

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Symmetrical and unsymmetrical diphosphinoamines of the type X2PN(R)PX2 and X2PN(R)YY′ offer vast scope for the synthesis of a variety of transition metal organometallic complexes. Diphosphinoamines can be converted into their dioxides which are also accessible from appropriate (chloro)phosphane oxide precursors. The diphosphazane dioxides form an interesting series of complexes with lanthanide and actinide elements. Structural and spectroscopic studies have been carried out on a wide range of transition metal complexes incorporating linear P-N-P ligands and judiciously functionalized cyclophosphazanes and cyclophosphazenes.


P-N-P framework ligands transition metal complexes diphosphinoamines