Journal of Chemical Sciences

, Volume 118, Issue 5, pp 375–384

Aniline incorporated silica nanobubbles

  • M. J. Rosemary
  • V. Suryanarayanan
  • Ian Maclarenb
  • T. Pradeep
Article

DOI: 10.1007/BF02711447

Cite this article as:
Rosemary, M.J., Suryanarayanan, V., Maclarenb, I. et al. J Chem Sci (2006) 118: 375. doi:10.1007/BF02711447

Abstract

We report the synthesis of stearate functionalized nanobubbles of SiO2 with a few aniline molecules inside, represented as C6H5NH2@SiO2@stearate, exhibiting fluorescence with red-shifted emission. Stearic acid functionalization allows the materials to be handled just as free molecules, for dissolution, precipitation, storage etc. The methodology adopted involves adsorption of aniline on the surface of gold nanoparticles with subsequent growth of a silica shell through monolayers, followed by the selective removal of the metal core either using sodium cyanide or by a new reaction involving halocarbons. The material is stable and can be stored for extended periods without loss of fluorescence. Spectroscopic and voltammetric properties of the system were studied in order to understand the interaction of aniline with the shell as well as the monolayer, whilst transmission electron microscopy has been used to study the silica shell.

Keywords

Silica nanoshellsanilinecore-shell particlesspectroscopic studiestransmission electron microscopycarbon onions

Copyright information

© Indian Academy of Sciences 2006

Authors and Affiliations

  • M. J. Rosemary
    • 1
  • V. Suryanarayanan
    • 1
  • Ian Maclarenb
    • 2
  • T. Pradeep
    • 1
  1. 1.DST Unit on Nanoscience, Department of Chemistry and Sophisticated Analytical Instrument FacilityIndian Institute of Technology MadrasChennai
  2. 2.Institute for Materials ScienceDarmstadt University of TechnologyDarmstadtGermany
  3. 3.Department of Physics and AstronomyUniversity of GlasgowGlasgowUK