Korean Journal of Chemical Engineering

, Volume 23, Issue 5, pp 736–740

Kinetic analysis of thermal decomposition of boric acid from thermogravimetric data

Authors

    • Department of Chemical Engineering, Engineering FacultyAtatürk University
  • Fatih Demir
    • Department of Chemical Engineering, Engineering FacultyAtatürk University
  • Murat Bilen
    • Department of Chemical Engineering, Engineering FacultyAtatürk University
    • Eti Holding A., Research and Development Dept.İstanbul Yolu üzeri
  • Hüseyin Okur
    • Department of Chemical Engineering, Engineering FacultyAtatürk University
Article

DOI: 10.1007/BF02705920

Cite this article as:
Sevim, F., Demir, F., Bilen, M. et al. Korean J. Chem. Eng. (2006) 23: 736. doi:10.1007/BF02705920

Abstract

The kinetic parameters of the thermal decomposition of boric acid have been investigated by using TGA data. Suzuki and Coats-Redfern methods have been applied for the kinetic investigation. It was determined that decomposition kinetics of boric acid occurred in two steps and both regions suitably fit a first-order kinetic model. According to Coats-Redfern method, the activation energy and frequency factor were found as 79.85 kJ·mol-1 and 3.82x 104 min-1 for region I and 4.79 kJ·mol-1 and 4.045 x 10-5 min-1 for region II, respectively. The activation energies and frequency factors were found as 4.45 kJ·mol-1 and 4.08 x108 min-1 for the Suzuki method.

Key words

Boric Acid Thermal Decomposition Suzuki Method Coats-Redfern Method

Copyright information

© Korean Institute of Chemical Engineering 2006