Abstract
From relative rates of acetone formation in the azomethane sensitized decomposition of methyl ethyl ketone at 290 °C, log10(k/cm3mol−1s−1)=5.3±0.4 for the methyl radical addition to methyl ethyl ketone has been determined.
Abstract
Из относительных скоростей образования ацетона при разложении метилэтилкетона при 290°C, сенсибилизированным азометаном, была определена константа скорости присоединения метильного радикала к метилэтилкетону. lg10к(см3 моль−1сек−1)=5,3±0,4.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
H. Knoll, R. Schliebs, K. Scherzer: React. Kinet. Catal. Lett.,8, 469 (1978).
H. Knoll, G. Richter, R. Schliebs: Int. J. Chem. Kinet., (in press).
A. C. Baldwin, J. R. Barker, D. M. Golden, D. G. Hendry: J. Phys. Chem.,81, 2483 (1977).
L. Batt, T. S. A. Islam, G. N. Rattray: Int. J. Chem. Kinet.,10, 931 (1978).
R. Renaud, L. C. Leitch: Can. J. Chem.,32, 545 (1954).
H. Knoll, K. Scherzer, G. Geiseler: Int. J. Chem. Kinet.,5, 271 (1973).
J. A. Kerr, M. Parsonage: Evaluated Kinetic Data on Gas Phase Hydrogen Transfer Reactions of Methyl Radicals. Butterworths, London 1976.
L. Batt, R. T. Milne: Int. J. Chem. Kinet.,8, 59 (1976).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Knoll, H. Methyl radical addition to methyl ethyl ketone. React Kinet Catal Lett 15, 431–435 (1981). https://doi.org/10.1007/BF02074146
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02074146