Reaction Kinetics and Catalysis Letters

, Volume 52, Issue 2, pp 295-302

First online:

Oxidative passivation of nickel in catalytic cracking by carbon dioxide

  • S. R. MirzabekovaAffiliated withInstitute of Petrochemical Processes
  • , A. Kh. MamedovAffiliated withInstitute of Petrochemical Processes
  • , M. I. RustamovAffiliated withInstitute of Petrochemical Processes

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A possibility to use CO2 as a nickel oxidative passivator for catalytic cracking has been shown for the first time. A model reaction of n-C7H16 cracking indicates that CO2 contributes to the stable activity ofMn-containing catalysts irrespective of their Ni content. Moreover, CO2 oxidizes metallic nickel, thus decreasing the deep cracking reaction and the content of low-molecular hydrocarbons.