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Topological aspects of chemical reactivity

Concertedness in pericyclic reactions

  • Topological Models in Chemistry
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Abstract

The technique of the so-called More O'Ferrall diagrams was modified by incorporating the framework of recently introduced topological theory of chemical reactivity. On the basis of this modification, a new simple criterion was introduced, allowing the unequivocal classification of the mechanisms of pericyclic reactions from the point of view of concertedness and/or nonconcertedness.

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Ponec, R., Strnad, M. Topological aspects of chemical reactivity. J Math Chem 8, 103–112 (1991). https://doi.org/10.1007/BF01166927

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