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An alternative construction of the Percus-Yevick equation based on the equilibrium BBGKY hierarchy

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Abstract

The existing derivations of the Percus-Yevick equation are not readily extendable into the nonequilibrium domain. In particular, the elegant Percus functional construction relies on a test particle theorem which lacks an exact nonequilibrium generalization. We propose here a new construction which utilizes some elementary ideas of functional expansions together with the equilibrium BBGKY hierarchy of equations. Also, we feel this new construction provides fresh insight into the physical basis of the equilibrium Percus-Yevick equation.

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References

  1. N. N. Bogoliubov, Problems of a Dynamical Theory in Statistical Physics, inStudies in Statistical Mechanics, Vol. 1, J. deBoar and G. E. Uhlenbeck, eds. (Wiley-Interscience, New York, 1962).

    Google Scholar 

  2. M. Born and H. S. Green,Proc. Roy. Soc. Land. A 188:10 (1946).

    Google Scholar 

  3. R. Brout and P. Carruthers,Lectures on the Many-Electron Problem (Wiley-Interscience, New York, 1963).

    Google Scholar 

  4. A. A. Broyles, S. U. Chung, and H. L. Sahlin,J. Chem. Phys. 27:2462 (1962).

    Google Scholar 

  5. P. Debye and E. Huckel,Phys. Z. 24:185 (1923).

    Google Scholar 

  6. I. Z. Fisher,Statistical Theory of Liquids (University of Chicago Press, Chicago, 1964).

    Google Scholar 

  7. H. L. Frisch and J. L. Lebowitz, eds.,The Equilibrium Theory of Classical Fluids (Benjamin, New York, 1964).

    Google Scholar 

  8. T. L. Hill,Statistical Mechanics (McGraw-Hill, New York, 1956).

    Google Scholar 

  9. J. G. Kirkwood,J. Chem. Phys. 14:180 (1946).

    Google Scholar 

  10. J. G. Kirkwood and Z. Salsburg,Disc. Faraday Soc. 15:28 (1953).

    Google Scholar 

  11. P. C. Martin, E. D. Siggia, and H. A. Rose,Phys. Rev. A 8:423 (1973).

    Google Scholar 

  12. I. Nezbeda,Czech. J. Phys. B 24:55 (1974).

    Google Scholar 

  13. B. R. A. Nijboer and L. Van Hove,Phys. Rev. 85:777 (1952).

    Google Scholar 

  14. L. S. Ornstein and F. Zernike,Proc. Akad. Sci. (Amsterdam) 17:793 (1914).

    Google Scholar 

  15. J. K. Percus and G. J. Yevick,Phys. Rev. 110:1 (1958).

    Google Scholar 

  16. J. K. Percus, The Pair Distribution Function in Classical Statistical Mechanics, inThe Equilibrium Theory of Classical Fluids, H. L. Frish and J. L. Lebowitz, eds. (Benjamin, New York, 1964).

    Google Scholar 

  17. L. A. Pipes and L. R. Harvill,Applied Mathematics for Engineers and Physicists (McGraw-Hill, New York, 1946).

    Google Scholar 

  18. H. N. V. Temperley, J. S. Rowlinson, and G. S. Rushbrooke, eds.,Physics of Simple Liquids (North-Holland, Amsterdam, 1968).

    Google Scholar 

  19. E. Thiele,J. Chem. Phys. 39:474 (1963).

    Google Scholar 

  20. H. D. Ursell,Proc. Camb. Phil. Soc. 23:685 (1927).

    Google Scholar 

  21. R. L. Varley,Phys. Lett. 66A:41 (1978); Toward a Nonequilibrium Theory of Liquids: A Nonequilibrium Analogue of the Percus-Yevick Equation, Ph.D. Thesis, Brandeis University (1976).

    Google Scholar 

  22. V. Volterra,Theory of Functionals (Dover, New York, 1959).

    Google Scholar 

  23. M. S. Wertheim,Phys. Rev. Lett. 10:321 (1963).

    Google Scholar 

  24. M. S. Wertheim,J. Math. Phys. 5:643 (1964).

    Google Scholar 

  25. E. T. Whittaker and G. N. Watson,A Course of Modern Analysis (Cambridge University Press, Cambridge, 1973).

    Google Scholar 

  26. W. W. Wood and F. R. Parker,J. Chem. Phys. 27:720 (1957).

    Google Scholar 

  27. J. Yvon,La Theorie Statistique des Fluides et l'Equation d'Etat (Hermann, Paris, 1935).

    Google Scholar 

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This research was supported in part by a grant from the Faculty Research Award Program of the City University of New York.

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Varley, R.L. An alternative construction of the Percus-Yevick equation based on the equilibrium BBGKY hierarchy. J Stat Phys 21, 87–100 (1979). https://doi.org/10.1007/BF01011483

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  • DOI: https://doi.org/10.1007/BF01011483

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