Influence of the concentration of aqua-ions of Fe(III) on the rate of decomposition of H2O2, inhibited by tetranitromethane
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- Plakhotnik, V.A. Russ Chem Bull (1974) 23: 473. doi:10.1007/BF00921125
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The kinetics of the decomposition of H2O2 in the presence of aqua-ions of Fe(III) and tetranitro-methane was investigated.
An intermediate product of the decomposition of hydrogen peroxide, inhibited by tetranitromethane-nitroform-captures free radicals and forms peroxonitrous acid, which induces autocatalysis in the system H2O2-Fe(III)-C(NO2)4.