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Mechanism of the AZO-coup ling of 2,6-dialkylphenols in nonaqueous medium

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The conditions of azo-coupling of 2,6-dialkylphenols in aprotonic medium were developed.

  2. 2.

    The kinetics of the azo-coupling of 2,6-dialkylphenols with p-benzoquinone diazide was studied spectrophotometrically.

  3. 3.

    The reaction of azo-coupling proceeds through the step of formation of an intermediate quinolide compound, the decomposition of which determines the summary rate of the process.

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Literature cited

  1. Modern Problems of Physical Organic Chemistry [Russian translation], Mir (1967).

  2. A. A. Volod'kin and V. V. Ershov, Izv. Akad. Nauk SSSR, Otd. Khim. N., 2022 (1962).

  3. G. A. Zlobina and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1666 (1964).

  4. G. A. Zlobina and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 189 (1966).

  5. H. Zollinger, Helv. Chim. Acta.,38, 1597 (1955);41, 2274 (1958).

    Google Scholar 

  6. S. Hünig, H. Geiger, and G. Kaupp, Liebigs Ann. Chem.,697, 116 (1966); S. Hünig and G. Kaupp, Tetrahedron,23, 1411 (1967).

    Google Scholar 

  7. R. Huisgen, G. Horeld, and L. Krause, Liebigs Ann. Chem.,562, 137 (1949);573, 163, 131 (1951).

    Google Scholar 

  8. W. Bradley and J. Thompson, Nature,178, 1069 (1956).

    Google Scholar 

  9. L. A. Kazitsyna, D. N. Klyueva, and K. V. Romanova, Dokl. Akad. Nauk SSSR,183, 105 (1968).

    Google Scholar 

  10. G. M. Bulgakova, Z. M. Maizus, and I. P. Skibida, Kinetika i Kataliz,7, 332 (1966).

    Google Scholar 

  11. N. M. Émanuél' and D. G. Knorre, Course in Chemical Kinetics [in Russian], Vysshaya Shkola (1962), p. 201.

  12. G. A. Nikiforov, L. S. Geidysh, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1132 (1968).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    L. S. Geidysh, G. A. Nikiforov & V. V. Ershov

Authors
  1. L. S. Geidysh
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  2. G. A. Nikiforov
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  3. V. V. Ershov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2716–2720, December, 1969.

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Geidysh, L.S., Nikiforov, G.A. & Ershov, V.V. Mechanism of the AZO-coup ling of 2,6-dialkylphenols in nonaqueous medium. Russ Chem Bull 18, 2552–2555 (1969). https://doi.org/10.1007/BF00912540

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  • DOI: https://doi.org/10.1007/BF00912540

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