Bulletin of the Academy of Sciences of the USSR, Division of chemical science

, Volume 18, Issue 12, pp 2552–2555

Mechanism of the AZO-coup ling of 2,6-dialkylphenols in nonaqueous medium

  • L. S. Geidysh
  • G. A. Nikiforov
  • V. V. Ershov
Physical Chemistry

DOI: 10.1007/BF00912540

Cite this article as:
Geidysh, L.S., Nikiforov, G.A. & Ershov, V.V. Russ Chem Bull (1969) 18: 2552. doi:10.1007/BF00912540

Conclusions

  1. 1.

    The conditions of azo-coupling of 2,6-dialkylphenols in aprotonic medium were developed.

     
  2. 2.

    The kinetics of the azo-coupling of 2,6-dialkylphenols with p-benzoquinone diazide was studied spectrophotometrically.

     
  3. 3.

    The reaction of azo-coupling proceeds through the step of formation of an intermediate quinolide compound, the decomposition of which determines the summary rate of the process.

     

Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • L. S. Geidysh
    • 1
  • G. A. Nikiforov
    • 1
  • V. V. Ershov
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR