Conclusions
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1.
In the oxidation of the acetates of the isomeric decahydro-1,2-dimethyl-4-vinyl-4-quinolinols with one molecular proportion of peracetic acid decahydro-1,2-dimethyl-4-vinyl-4-quinolinol 1-oxides are formed.
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2.
In the oxidation of the isomeric decahydro-1,2-dimethyl-4-vinyl-4-quinolinols with performic acid the corresponding 4-(epoxyethyl)decahydro-1,2-dimethyl-4-quinolinols are formed.
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3.
In acid hydrolysis 4-(epoxyethyl)decahydro-1,2-dimethyl-4-quinolinols form the corresponding 4-(1,2-dihydroxyethyl)decahydro-1,2-dimethyl-4-quinolinols.
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A. A. Akhrem, L. I. Ukhova, and N. F Uskova, Izv. AN SSSR, Otd. Khim. Nauk,1962, 304.
A. A. Akhrem, L. I. Ukhova, N. F. Marchenko, and N. F. Uskova,Izv. AN SSSR, Ser. Khim., 1968,2789.
V. I. Zaretskii, N. S. Vul'fson, V. G. Zapkin, A. A. Akhrem, L. I. Ukhova, and N. F. Uskova, Izv. AN SSSR, Ser. Khim.,1968, 2164.
G. Fodor, G. Janzso, et al., J. Chem. Soc.,1959, 3461.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2781–1785, December, 1968.
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Akhrem, A.A., Ukhova, L.I., Uskova, N.F. et al. Heterocyclic analogs of corticosteroids. Russ Chem Bull 17, 2633–2636 (1968). https://doi.org/10.1007/BF00907789
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DOI: https://doi.org/10.1007/BF00907789