Catalysis Letters

, Volume 5, Issue 2, pp 229–235

Hydrogen pressure-dependence in the ring-opening reactions of substituted cyclopropanes over Rh/SiO2 catalyst

  • Ferenc Notheisz
  • István Pálinkó
  • Mihály Bartók
Article

DOI: 10.1007/BF00763957

Cite this article as:
Notheisz, F., Pálinkó, I. & Bartók, M. Catal Lett (1990) 5: 229. doi:10.1007/BF00763957
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Abstract

The hydrogen coverage and the structures of the reactants influence the selectivity and mechanism of the ring-opening reactions of ethyl-(ECP),cis-1,2-dimethyl-(cDMCP),trans1,2-dimethyl-(tDMCP), 1,1-dimethyl-(1, 1DMCP) and 1, 1, 2, 2-tetramethylcyclopropane (TMCP) over Rh/SiO2 catalyst; a new phenomenon was observed for the transformations of ECP,tDMCP and 1, 1DMCP, viz. the turnover frequency vs. H2 pressure functions pass through a minimum.

Hydrogenative ring-openingRh on silica catalystalkyl-substituted cyclopropaneshydrogen pressure effect

Copyright information

© J.C. Baltzer A.G. Scientific Publishing Company 1990

Authors and Affiliations

  • Ferenc Notheisz
    • 1
  • István Pálinkó
    • 1
  • Mihály Bartók
    • 1
  1. 1.Department of Organic ChemistryJózsef Attila UniversitySzeged, Dómtér 8Hungary