Article

Catalysis Letters

, Volume 17, Issue 1, pp 29-37

Strong metal-support interaction in Ni/TiO2 catalysts: in situ EXAFS and related studies

  • T. ArunarkavalliAffiliated withSolid State and Structural Chemistry Unit and CSIR Centre of Excellence in Chemistry, Indian Institute of Science
  • , G. U. KulkarniAffiliated withSolid State and Structural Chemistry Unit and CSIR Centre of Excellence in Chemistry, Indian Institute of Science
  • , G. SankarAffiliated withSolid State and Structural Chemistry Unit and CSIR Centre of Excellence in Chemistry, Indian Institute of Science
  • , C. N. R. RaoAffiliated withSolid State and Structural Chemistry Unit and CSIR Centre of Excellence in Chemistry, Indian Institute of Science

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Abstract

In situ EXAFS and X-ray diffraction investigations of Ni/TiO2 catalysts show that NiTiO3 is formed as an intermediate during calcination of catalyst precursors prepared by the wet-impregnation method; the intermediate is not formed when ion-exchange method is used for the preparation. On hydrogen reduction, NiTiO3 gives rise to Ni particles dispersed in the TiO2(rutile) matrix. The occurrence of the anatase-rutile transformation of the TiO2 support, the formation and subsequent decomposition/reduction of NiTiO3 as well as the unique interface properties of the Ni particles are all factors of importance in giving rise to metal-support interaction. Active TiO2(anatase) prepared from gel route gives an additional species involving Ni3+.

Keywords

SMSI strong metal-support interaction Ni/TiO2 catalyst EXAFS of catalysts