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The geochemistry and petrogenesis of K-rich alkaline volcanics from the Batu Tara volcano, eastern Sunda arc

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Abstract

Mineralogical, major and trace element, and isotopic data are presented for leucite basanite and leucite tephrite eruptives and dykes from the Batu Tara volcano, eastern Sunda arc. In general, the eruptives are markedly porphyritic with phenocrysts of clinopyroxene, olivine, leucite ±plagioclase±biotite set in similar groundmass assemblages. These K-rich alkaline volcanics have high concentrations of large-ion-lithophile (LIL), light rare earth (LRE) and most incompatible trace elements, and are characterized by high 87Sr/86Sr (0.70571–0.70706) and low 143Nd/ 144Nd (0.512609–0.512450) compared with less alkaline volcanics from the Sunda arc. They also display the relative depletion of Ti and Nb in chondrite-normalized plots which is a feature of subalkaline volcanics from the eastern Sunda arc and arc volcanics in general. Chemical and mineralogical data for the Batu Tara K-rich rocks indicate that they were formed by the accumulation of variable amounts of phenocrysts in several melts with different major and trace element compositions. The compositions of one of these melts estimated from glass inclusions in phenocrysts is relatively Fe-rich (100 Mg/(Mg + Fe2+)=48–51) and is inferred to have been derived from a more primitive magma by low-pressure crystal fractionation involving olivine, clinopyroxene and spinel. Mg-rich (mg ∼90) and Cr-rich (up to 1.7 wt. % Cr2O3) zones in complex oscillatory-zoned clinopyroxene phenocrysts probably also crystallized from such a magma. The marked oscillatory zoning in the clinopyroxene phenocrysts is considered to be the result of limited mixing of relatively ‘evolved’ with more primitive magmas, together with their phenocrysts, along interfaces between discrete convecting magma bodies.

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References

  • Anderson AT (1979) Water in some hypersthenic magmas. J Geol 87:509–531

    Google Scholar 

  • Baldridge WS, Carmichael ISE, Albee AL (1981) Crystallization paths of leucite-bearing lavas: examples from Italy. Contrib Mineral Petrol 76:321–335

    Google Scholar 

  • Barton M, Varekamp JC, van Bergen MJ (1982) Complex zoning of clinopyroxenes in the lavas of Vulsini, Latium, Italy: evidence for magma mixing. J Volcanol Geotherm Res 14:361–388

    Google Scholar 

  • Ben Avraham Z, Emery KO (1973) Structural framework of the Sunda shelf. Bull Am Assoc Petrol Geol 57:2323–2366

    Google Scholar 

  • Brouwer HA (1940) Geological and petrological investigations of alkali and calc-alkali rocks of the islands Adonara, Lomblen and Batoe Tara. In:Geological Expedition of the University of Amsterdam to the Lesser Sunda Islands, 2:1–94

    Google Scholar 

  • Brown FH, Carmichael ISE (1969) Quaternary volcanoes of the Lake Rudolf Region: pt 1, the basanite-tephrite series of the Korath Range. Lithos 2:239–260

    Google Scholar 

  • Carmichael ISE, Turner FJ, Verhoogen J (1974) Igneous Petrology. McGraw-Hill, New York, p 739

    Google Scholar 

  • Conrad WK, Kay RW (1984) Ultramafic and mafic inclusions from Adak Island: crystallization history, and implications for the nature of primary magmas and crustal evolution in the Aleutian arc. J Petrol 25:88–125

    Google Scholar 

  • Cox KG, Hawkesworth CJ, O'Nions RK, Appleton JD (1976) Isotopic evidence for the derivation of some Roman region volcanics from anomalously enriched mantle. Contrib Mineral Petrol 56:173–180

    Google Scholar 

  • Cundari A (1973) Petrology of the leucite-bearing lavas in New South Wales. J Geol Soc Aust 20:465–492

    Google Scholar 

  • Cundari A (1980) Role of subduction in the genesis of leucitebearing rocks. Facts or fashion. Contrib Mineral Petrol 73:432–434

    Google Scholar 

  • Curray JR, Shor GG, Raitt RW, Henry M (1977) Seismic refraction and reflection studies of crustal structure of the eastern Sunda and western Banda arcs. J Geophys Res 82:2479–2489

    Google Scholar 

  • Dal Negro A, Carbonin S, Salviulo G, Piccirillo EM, Cundari A (1985) Crystal chemistry and site configuration of the clinopyroxene from leucite-bearing rocks and related genetic significance: the Sabatini lavas, Roman region, Italy. J Petrol 26:1027–1040

    Google Scholar 

  • Dal Negro A, Cundari A, Piccirillo EM, Molin GM, Uliana D (1986) Distinctive crystal chemistry and site configuration of the clinopyroxene from alkali basaltic rocks: the Nyambeni clinopyroxene suite, Kenya. Contrib Mineral Petrol 92:35–43

    Google Scholar 

  • Edgar AD (1980) Role of subduction in the genesis of leucitebearing rocks: Discussion. Contrib Mineral Petrol 73:429–431

    Google Scholar 

  • Foden JD (1986) The petrology of Tambora Volcano, Indonesia: A model for the 1815 eruption. J Volcanol Geotherm Res 27:1–41

    Google Scholar 

  • Foden JD, Varne R (1980) Petrogenetic and tectonic implications of near coeval calc-alkaline to highly alkaline volcanism on Lombok and Sumbawa Islands in the eastern Sunda arc. In: Barber AJ, Wiryosujono S (eds) The Geology and Tectonics of Eastern Indonesia. Geological Research and Development Centre, Spec. Publ. 2:135–152

  • Foley SF (1985) The oxidation state of lamproitic magmas. Tschermaks Mineral Petrog Mitt 34:217–238

    Google Scholar 

  • Foley SF, Venturelli G, Green DH, Toscani L (1987) The ultrapotassic rocks: Characteristics, classification, and constraints for petrogenetic models. Earth Sci Rev 24:81–134

    Google Scholar 

  • Gill JB (1981) Orogenic Andesites and Plate Tectonics. Springer, Berlin Heidelberg New York, p 390

    Google Scholar 

  • Hawkesworth CJ, Vollmer R (1979) Crustal contamination versus enriched mantle: 143Nd/144Nd and 87Sr/86Sr evidence from the Italian volcanics. Contrib Mineral Petrol 69:151–165

    Google Scholar 

  • Holm PM, Lou S, Nielsen A (1982) The geochemistry and petrogenesis of the lavas of the Vulsinian district, Roman Province, Central Italy. Contrib Mineral Petrol 80:367–378

    Google Scholar 

  • Huppert HE, Sparks RSJ (1984) Double-diffusive convection due to crystallization in magmas. Ann Rev Earth Planet Sci 12:11–37

    Google Scholar 

  • Irving AJ, Green DH (1976) Geochemistry and petrogenesis of the Newer Basalts of Victoria and South Australia. J Geol Soc Aust 23:45–66

    Google Scholar 

  • James DE (1981) The combined use of oxygen and radiogenic isotopes as indicators of crustal contamination. Ann Rev Earth Planet Sci 9:311–344

    Google Scholar 

  • Jaques AL, Lewis JD, Smith CB, Gregory GP, Ferguson J, Chappell BW, McCulloch MT (1984) The diamond-bearing ultrapotassic (lamproitic) rocks of the West Kimberley region, Western Australia. In: Kornprobst J (ed) Kimberlites I: kimberlites and related rocks. Elsevier, Amsterdam, pp 225–254

    Google Scholar 

  • Kuehner SM, Edgar AD, Arima M (1981) Petrogenesis of the ultrapotassic rocks from the Leucite Hills, Wyoming. Am Mineral 66:663–677

    Google Scholar 

  • Lasaga AC (1983) Geospeedometry: an extension of geothermometry. In: Saxena SK (ed) Kinetics and Equilibrium in Mineral Reactions. Springer, Berlin Heidelberg New York, pp 81–114

    Google Scholar 

  • Luth WC (1967) Studies in the system KAlSiO4-Mg2SiO4- SiO2-H2O. I. Inferred phase relations and petrologic applications. J Petrol 8:372–416

    Google Scholar 

  • Mertes H, Schmincke HU (1985) Mafic potassic lavas of the Quaternary West Eifel volcanic field. Contrib Mineral Petrol 89:330–345

    Google Scholar 

  • Mitchell RH, Bell K (1976) Rare earth element geochemistry of potassic lavas from the Birunga and Toro-Ankole regions of Uganda, Africa. Contrib Mineral Petrol 58:293–303

    Google Scholar 

  • Nicholls IA, Whitford DJ (1983) Potassium-rich volcanic rocks of the Muriah complex, Java, Indonesia: products of multiple magma sources? J Volcanol Geotherm Res 18:337–359

    Google Scholar 

  • Nixon P, Thirlwall MF, Buckley F, Davies CJ (1984) Spanish and Western Australian lamproites: aspects of whole rock geochemistry. In: Kornprobst J (ed) Kimberlites I: Kimberlites and Related Rocks. Elsevier, Amsterdam, pp 285–296

    Google Scholar 

  • Norrish K, Chappel BW (1977) X-ray fluorescence spectrometry. In: Zussman J (ed) Physical Methods in Determinative Mineralogy (2nd ed). Academic Press, London, pp 201–272

    Google Scholar 

  • O'Nions RK, Carter SR, Evensen NM, Hamilton PJ (1979) Geochemical and cosmochemical applications of Nd isotope analysis. Ann Rev Earth Planet Sci 7:11–38

    Google Scholar 

  • Pearce JA, Cann JR (1973) Tectonic setting of volcanic rocks determined using trace element analyses. Earth Planet Sci Lett 19:290–300

    Google Scholar 

  • Perfit MR, Gust DA, Bence AE, Arculus RJ, Taylor SR (1980) Chemical characteristics of island arc basalts: implications for mantle sources. Chem Geol 30:227–256

    Google Scholar 

  • Poli G, Frey FA, Ferrara G (1984) Geochemical characteristics of the South Tuscany (Italy) Volcanic Province: constraints on lava petrogenesis. Chem Geol 43:203–221

    Google Scholar 

  • Robinson P, Higgins NC, Jenner GA (1986) Determination of rareearth elements, yttrium and scandium in rocks by an ion exchange-X-ray fluorescence technique. Chem Geol 55:121–137

    Google Scholar 

  • Roeder PL, Emslie RF (1970) Olivine-liquid equilibria. Contrib Mineral Petrol 29:275–289

    Google Scholar 

  • Rogers NW, Hawkesworth CJ, Parker RJ, Marsh JS (1985) The geochemistry of potassic lavas from Vulsini, central Italy and implications for mantle enrichment processes beneath the Roman region. Contrib Mineral Petrol 90:244–257

    Google Scholar 

  • Sack RO, Carmichael ISE (1984) Fe2+⇄Mg2+ and TiAl2⇄MgSi2 exchange reactions between clinopyroxenes and silicate melts. Contrib Mineral Petrol 90:244–257

    Google Scholar 

  • Sack RO, Walker DA, Carmichael ISE (1987) Experimental petrology of alkalic lavas: constraints on cotectics of multiple saturation in natural basic liquids. Contrib Mineral Petrol 96:1–23

    Google Scholar 

  • Sack RO, Carmichael ISE, Rivers M, Ghiorso MS (1980) Ferricferrous equilibria in natural silicate liquids at 1 bar. Contrib Mineral Petrol 75:369–376

    Google Scholar 

  • Sheraton JW, Cundari A (1980) Leucitites from Gaussberg, Antarctica. Contrib Mineral Petrol 71:417–427

    Google Scholar 

  • Sorensen H (1974) The Alkaline Rocks. John Wiley and Sons, London

    Google Scholar 

  • Stolz AJ (1985) The role of fractional crystallization in the evolution of the Nandewar Volcano, North-eastern New South Wales, Australia. J Petrol 26:1002–1026

    Google Scholar 

  • Stolz AJ (1986) Mineralogy of the Nandewar Volcano, northeastern New South Wales, Australia. Mineral Mag 50:241–255

    Google Scholar 

  • Sun SS (1980) Lead isotopic study of young volcanic rocks from mid-ocean ridges, ocean islands and island arcs. Phil Trans R Soc Lond A 297:409–445

    Google Scholar 

  • Takahashi E, Kushiro I (1983) Melting of a dry peridotite at high pressures and basalt magma genesis. Am Mineral 68:859–879

    Google Scholar 

  • Thompson RN (1982) Magmatism of the British Tertiary Volcanic Province. Scott J Geol 18:49–107

    Google Scholar 

  • Varne R, Foden JD (1986) Geochemical and isotopic systematics of eastern Sunda arc volcanics: implications for mantle sources and mantle mixing processes. In: Wezel FC (ed) The Origin of Arcs. Elsevier, Amsterdam, pp 159–189

    Google Scholar 

  • Venturelli G, Capedri S, Di Battistini G, Crawford AJ, Kogarko LN, Celestini S (1984) The ultrapotassic rocks from southeastern Spain. Lithos 17:37–54

    Google Scholar 

  • Ware NG (1981) Computer programs and calibration with the PIBS technique for quantitative electron probe analysis using a lithium-drifted silicon detector. Computers and Geosciences 7:167–184

    Google Scholar 

  • Whitford DJ (1975a) Geochemistry and petrology of volcanic rocks from the Sunda arc, Indonesia. Unpublished Ph.D. thesis, Australian National University, p 449

  • Whitford DJ (1975b) Strontium isotopic studies of the volcanic rocks of the Sunda arc, Indonesia, and their petrogenetic implications. Geochim Cosmochim Acta 39:1287–1302

    Google Scholar 

  • Whitford DJ, Foden JD, Varne R (1978) Sr isotope geochemistry of calcalkaline and alkaline lavas from the Sunda arc in Lombok and Sumbawa, Indonesia. Carneg Inst Wash Ybk 77:613–620

    Google Scholar 

  • Whitford DJ, Nicholls IA, Taylor SR (1979) Spatial variations in the geochemistry of Quaternary lavas across the Sunda arc in Java and Bali. Contrib Mineral Petrol 70:341–356

    Google Scholar 

  • Whitford DJ, White WM, Jezek PA (1981) Neodymium isotopic composition of Quaternary island arc lavas from Indonesia. Geochim Cosmochim Acta 45:989–995

    Google Scholar 

  • Wilkinson JFG, Stolz AJ (1983) Low-pressure fractionation of strongly undersaturated alkaline ultrabasic magma: the olivinemelilite-nephelinite at Moiliili, Oahu, Hawaii. Contrib Mineral Petrol 83:363–374

    Google Scholar 

  • Zindler A, Hart SR (1986) Chemical geodynamics. Ann Rev Earth Planet Sci 14:493–571

    Google Scholar 

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Stolz, A.J., Varne, R., Wheller, G.E. et al. The geochemistry and petrogenesis of K-rich alkaline volcanics from the Batu Tara volcano, eastern Sunda arc. Contr. Mineral. and Petrol. 98, 374–389 (1988). https://doi.org/10.1007/BF00375187

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