Skip to main content
Log in

An upper limit on the HCl near-surface mixing ratio over the Atlantic measured using TDLAS

  • Published:
Journal of Atmospheric Chemistry Aims and scope Submit manuscript

Abstract

A study of the gas phase mixing ratio of hydrochloric acid was made during the 1988 Polarstern expedition using tunable diode laser absorption spectroscopy (TDLAS). The measurements were made 22 m above sea level at 28° N, 30° W. The signal-to-noise ratio was unity for <50 pptv HCl, but because of wall effects in the sampling system, only an upper limit for the HCl mixing ratio of <250 pptv can be stated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Brassington, D. J., 1989, Measurements of atmospheric HCl and NH3 with a mobile tunable diode laser system, in R., Grisar, G., Schmidtke, M., Tacke, and G., Restelli (eds.), Monitoring of Gaseous Pollutants by Tunable Diode Lasers, Kluwer Academic Publishers, Dordrecht, pp. 16–24.

    Google Scholar 

  • Brimblecombe, P. and Clegg, L., 1988, The solubility and behaviour of acid gases in the marine acrosol, J. Atmos. Chem. 7, 1–18.

    Google Scholar 

  • Cicerone, R. J., 1981, Halogens in the atmosphere, Rev. Geophys. Space Phys. 19 (1), 123–129.

    Google Scholar 

  • Farmer, C. B., Raper, O. F. and Norton, R. H., 1976, Spectroscopic detection and vertical distribution of HCl in the troposphere and stratosphere, Geophys. Res. Lett. 3 (1), 13–16.

    Google Scholar 

  • Freid, A., Sams, R. and Berg, W., 1983, Application of tunable diode laser absorption for trace stratospheric measurements of HCl: laboratory results, Applied Optics 23, 1867–1880.

    Google Scholar 

  • Harris, G. W., Klemp, D., Zenker, T., and Burrows, J. P., 1992, Polarstern 1988: Tunable diode laser measurements of trace gases during the 1988 Polarstern cruise and intercomparisons with other methods, J. Atmos. Chem. 15, 315–326.

    Google Scholar 

  • Junge, C. E., 1957, Chemical analysis of aerosol particles and gas traces on the island of Hawaii, Tellus 9, 528–537.

    Google Scholar 

  • Keene, W. C., Pszenny, A. A. P., Jacob, D., Duce, R. A., Galloway, J. N., Schultz-Tokos, J. J., Sievering, H., and Boatman, J. F., 1990, The geochemical cycling of reactive chlorine through the marine troposphere, Global Biogeochemical Cycles 4, 407–430.

    Google Scholar 

  • Marché, P., Barbe, A., Secroun, C., Corr, J., and Jouve, P., 1980, Ground based spectroscopic measurement of HCl, Geophys. Res. Lett. 7 (1 l), 869–872.

    Google Scholar 

  • Matusca, P., Schwarz, B., and Bachmann, K., 1984, Measurements of the diurnal concentration variation of gaseous HCl in the sub-nanogram range, Atmos. Environ. 18, 1667–1675.

    Google Scholar 

  • Müller, K. P. and Rudolph, J., 1990, Measurements of peroxyacetyl nitrate in the marine atmosphere, in G., Restelli and G., Angeletti (eds.), Physico-Chemical Behaviour of Atmospheric Pollutants, Kluwer Academic Publishers, Dordrecht, pp. 705–710.

    Google Scholar 

  • Papenbrock, T., and Stuhl, F., 1990, Detection of HNO3 in air by a laser-photolysis fragmentation fluorescence (LPPF) method, in G., Restelli and G., Angeletti (eds.), Physico-Chemical Behaviour of Atmospheric Pollutants, Kluwer Academic Publishers, Dordrecht, pp. 651–656.

    Google Scholar 

  • Singh, H. B., and Kasting, J. F., 1988, Chlorine-hydrocarbon photochemistry in the marine troposphere and lower stratosphere, J. Atmos. Chem. 7, 261–285.

    Google Scholar 

  • Vierkorn-Rudolph, B., Rudolph, J., Meixner, F. J., Bachmann, K., and Schwarz, B., 1984a, Vertical and horizontal profiles of hydrogen chloride in the Mediterranean Region, in G., Restelli and G., Angeletti (eds.), Physico-Chemical Behaviour of Atmospheric Pollutants, D. Reidel, Dordrecht, pp. 433–440.

    Google Scholar 

  • Vierkorn-Rudolph, B., Bachmann, K., Schwarz, B., and Meixner, F. X., 1984b, Vertical profiles of hydrogen chloride in the troposphere, J. Atmos. Chem. 2, 47–63.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Harris, G.W., Klemp, D. & Zenker, T. An upper limit on the HCl near-surface mixing ratio over the Atlantic measured using TDLAS. J Atmos Chem 15, 327–332 (1992). https://doi.org/10.1007/BF00115402

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00115402

Key words

Navigation