Journal of the Iranian Chemical Society

, Volume 11, Issue 1, pp 263–269

Palladium nanoparticles supported on gum arabic as a reusable catalyst for solvent-free Mizoroki-Heck reaction

Authors

    • Faculty of Chemistry, Bu-Ali Sina University
    • Department of ChemistryPayame Noor University (PNU)
  • Arash Ghaderi
    • Department of Chemistry, College of SciencesHormozgan University
  • Leila Roshani
    • Faculty of Chemistry, Bu-Ali Sina University
Original Paper

DOI: 10.1007/s13738-013-0296-3

Cite this article as:
Khazaei, A., Rahmati, S., Ghaderi, A. et al. J IRAN CHEM SOC (2014) 11: 263. doi:10.1007/s13738-013-0296-3

Abstract

Palladium nanoparticles (2–8 nm) supported on gum arabic has been prepared under green conditions in water. Gum arabic has been used as both support and reducing agent. These nanoparticles have been characterized by UV–Vis, XRD and EDX spectra as well as SEM and TEM images. The nanoparticles have been applied as the catalyst in Mizoroki-Heck reaction of different aryl halides (I, Br, Cl) with butyl acrylate in the presence of n-Pr3N under solvent-free conditions at 140 °C. The reusability of the catalyst was also checked for five consecutive runs.

Keywords

Palladium nanoparticlesGum arabicMizoroki-Heck reactionSolvent-free

Supplementary material

13738_2013_296_MOESM1_ESM.doc (8.2 mb)
Supplementary material 1 (DOC 8370 kb)

Copyright information

© Iranian Chemical Society 2013