, Volume 28, Issue 2, pp 187-192

Influence of Mg and Ti on the microstructure and electrochemical performance of aluminum alloy sacrificial anodes

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Abstract

The experiments focused on the influence of magnesium and titanium as additional alloying elements on the microstructure and electrochemical behavior of Al-Zn-In sacrificial anodes. The electrochemical behavior of the aluminum sacrificial anode with 3 wt.% sodium chloride solution was studied by electrochemical impedance spectroscopy (EIS) tests. It was found that a microstructure with few precipitates and refined grains could be achieved by adding 1 wt.% Mg and 0.05 wt.% Ti to the Al-Zn-In alloy, resulting in the improved current capacity and efficiency of the alloy. The equivalent circuit based on the EIS experimental data revealed less corrosion and lower adsorbed corrosion production on the surface of the aluminum alloy with a combination of 1 wt.% Mg and 0.05 wt.% Ti, which suggested that the corrosion behavior seemed to be strongly related to the presence of precipitate particles in the aluminum alloy, and moderate amounts of precipitate particles could be beneficial to the electrochemical performance of the aluminum alloy sacrificial anode.