Nano Research

, Volume 4, Issue 3, pp 308–314

Linear strain-gradient effect on the energy bandgap in bent CdS nanowires

  • Qiang Fu
  • Zi Yue Zhang
  • Liangzhi Kou
  • Peicai Wu
  • Xiaobing Han
  • Xinli Zhu
  • Jingyun Gao
  • Jun Xu
  • Qing Zhao
  • Wanlin Guo
  • Dapeng Yu
Research Article

DOI: 10.1007/s12274-010-0085-6

Cite this article as:
Fu, Q., Zhang, Z.Y., Kou, L. et al. Nano Res. (2011) 4: 308. doi:10.1007/s12274-010-0085-6

Abstract

Although possible non-homogeneous strain effects in semiconductors have been investigated for over a half century and the strain-gradient can be over 1% per micrometer in flexible nanostructures, we still lack an understanding of their influence on energy bands. Here we conduct a systematic cathodoluminescence spectroscopy study of the strain-gradient induced exciton energy shift in elastically curved CdS nanowires at low temperature, and find that the red-shift of the exciton energy in the curved nanowires is proportional to the strain-gradient, an index of lattice distortion. Density functional calculations show the same trend of band gap reduction in curved nanostructures and reveal the underlying mechanism. The significant linear strain-gradient effect on the band gap of semiconductors should shed new light on ways to tune optical-electronic properties in nanoelectronics.
https://static-content.springer.com/image/art%3A10.1007%2Fs12274-010-0085-6/MediaObjects/12274_2010_85_Fig1_HTML.gif

Keywords

Strain-gradient effectCdS nanowirebending deformationcathodoluminescence

Supplementary material

12274_2010_85_MOESM1_ESM.pdf (797 kb)
Supplementary material, approximately 1.06 MB.

Copyright information

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  • Qiang Fu
    • 1
  • Zi Yue Zhang
    • 2
  • Liangzhi Kou
    • 2
  • Peicai Wu
    • 1
  • Xiaobing Han
    • 1
  • Xinli Zhu
    • 1
  • Jingyun Gao
    • 1
  • Jun Xu
    • 1
  • Qing Zhao
    • 1
  • Wanlin Guo
    • 2
  • Dapeng Yu
    • 1
  1. 1.State Key Laboratory for Mesoscopic Physics, and Electron Microscopy Laboratory, Department of PhysicsPeking UniversityBeijingChina
  2. 2.Institute of NanoscienceNanjing University of Aeronautics and AstronauticsNanjingChina