Journal of Coatings Technology and Research

, Volume 8, Issue 1, pp 83–95

A mechanistic study of degradation of a typical automotive clearcoat caused by bird droppings

  • Hossein Yari
  • Mohsen Mohseni
  • Bahram Ramezanzadeh
Article

DOI: 10.1007/s11998-010-9273-2

Cite this article as:
Yari, H., Mohseni, M. & Ramezanzadeh, B. J Coat Technol Res (2011) 8: 83. doi:10.1007/s11998-010-9273-2

Abstract

This study aims at investigating the degradation mechanism of an automotive clearcoat caused by bird droppings. Natural bird droppings and their synthetic equivalent (pancreatin) were utilized for this purpose. The presence of highly-etched areas on the surface of coatings and structural variations of clearcoat after being attacked by these materials corresponded to a catalyzed hydrolytic degradation. This finding was obtained using different analytical techniques. Based on these studies, three possible hypotheses were presented, including acid catalysis, metal ion catalysis, and enzymatic catalysis. The conditions required for the occurrence of each hypothesis were discussed. It was found that acid and metal ions have a weak contribution to catalyze the hydrolysis reaction of clearcoat, whereas enzymes existing in bird droppings were mainly responsible for this hydrolytic degradation.

Keywords

Enzymatic degradation Bird droppings Automotive coating Hydrolysis Pancreatin 

Copyright information

© ACA and OCCA 2010

Authors and Affiliations

  • Hossein Yari
    • 1
  • Mohsen Mohseni
    • 1
  • Bahram Ramezanzadeh
    • 1
  1. 1.Polymer Engineering and Color Technology DepartmentAmirkabir University of TechnologyTehranIran

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