Skip to main content
Log in

Investigation of the properties of UV-curing acrylate-terminated unsaturated polyester coatings by utilizing an experimental design methodology

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

The effect of the extent of internal unsaturation and branching on the properties of the acrylated polyester films was investigated. Polyester acrylate resins were prepared based on adipic acid, maleic anhydride, neopentyl glycol, trimethylolpropane, and acrylic acid. As the reactive diluent, trimethylolpropane triacrylate (TMPTA) was used. Experiments were planned according to the three-factor, three-level Box-Behnken design. Coating film properties were evaluated in terms of the independent variables, amount of branching, internal unsaturation, and reactive diluent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Scheme 1

Similar content being viewed by others

References

  1. Chiocchetti P (1988) Radiation Curing Coatings in the Wood Industry, Polym. Paint Col. J. 178:4216

    Google Scholar 

  2. Roffey GC 1982 Photopolymerization of Surface Coatings. John Wiley and Sons, New York

    Google Scholar 

  3. Webster G (1997) Chemistry and Technology of UV and EB Formulation for Coatings, Inks and Paints: Prepolymers and Reactive Diluents for UV and EB Curable Formulations. John Wiley and Sons, New York

    Google Scholar 

  4. Cook DW, Lau M, Mehrabi M, Dean K, Zipper M (2001) Control of Gel Time and Exothermic Behavior During Cure of Unsaturated Polyester Resins, Polym. Int. 50:129

    Article  CAS  Google Scholar 

  5. Wicks ZW, Jones FN, Pappas SP, 1999 Organic Coatings Science and Technology. 2nd edn., John Wiley and Sons, New York

    Google Scholar 

  6. Adams, RM, Cremaschi, JA, Phan, XT, Riggs, GA, PCT Int. Appl.; Reichhold, Inc., USA. Wo 32 pp (2000)

  7. Mehnert R, Pincus A, Janorsky I, Stowe R, Berejka A (1998) Chemistry and Technology of UV and EB Formulations for Coatings, Inks, and Paints: UV and EB Curing Technology and Equipment. John Wiley and Sons, New York

    Google Scholar 

  8. Hild G, Okasha R (1985) Free Radical Crosslinking Copolymerization in the Post-Gel State, 3. Swelling and Mechanical Properties of Polystyrene Networks, Macromol. Chem. 186:389

    Article  CAS  Google Scholar 

  9. Muzumdar SV, Lee LJ (1991) Prediction of Gel-Time in the Cure of Unsaturated Polyester Resins: Phenomenological Modeling vs. Statistical Analysis, Polym. Eng. Sci. 31:1647

    Article  CAS  Google Scholar 

  10. Liu SB, Yu TL (1995) Study of the Microgelation of Unsaturated Polyester Resins by Dynamic Light Scattering, Macromol. Chem. Phys. 196:1307

    CAS  Google Scholar 

  11. Yang YS, Suspene L (1991) Curing of Unsaturated Polyester Resins: Viscosity Studies and Simulations in Pre-Gel State, Polym. Eng. Sci. 31:321

    Article  CAS  Google Scholar 

  12. Chen JS, Yu TL (1997) Microgellation of Unsaturated Polyester Resins by Static and Dynamic Light Scattering, J. Appl. Polym. Sci. 69:871

    Article  Google Scholar 

  13. Brill RP, Palmese GR (2000) An Investigation of Vinyl–Ester & Bond; Styrene Bulk Copolymerization Cure Kinetics Using Fourier Transform Infrared Spectroscopy, J. Appl. Polym. Sci. 76:1572

    Article  CAS  Google Scholar 

  14. Simon GP, Allen PEM, Williams DRG (1991) Properties of Dimethacrylate Copolymers of Varying Crosslink Density, Polymer 32:2577

    Article  CAS  Google Scholar 

  15. Young JS, Bowman CN (1999) Effect of Polymerization Temperature and Cross-Linker Concentration on Reaction Diffusion Controlled Termination, Macromolecules 32:6073

    Article  CAS  Google Scholar 

  16. Zlatanic A, Djonlagic J (1997) Synthesis and Characterization of Acrylate-Terminated Unsaturated Copolyesters, Macromol. Chem. Phys. 198:1775

    Article  CAS  Google Scholar 

  17. Djonlagic J, Zlatanic A, Dunjic B (1998) Rheological Behavior of Cured Acrylate-Terminated Unsaturated Copolyesters, Macromol. Chem. Phys. 199:2029

    Article  CAS  Google Scholar 

  18. Zlatanic A, Dunjic B, Djonlagic J (1999) Rheological Study of the Copolymerization Reaction of Acrylate-Terminated Unsaturated Copolyesters with Styrene, Macromol. Chem. Phys. 200:2048

    Article  CAS  Google Scholar 

  19. Peinado C, Alonso A, Salvador EF, Baselga J, Catalina F (2002) Following In-Situ Photoinitiated Polymerization of Multifunctional Acrylic Monomers by Fluorescence and Photocalorimetry Simultaneously, Polymer 43:5355

    Article  CAS  Google Scholar 

  20. Kannurpatti AR, Anseth JW, Bowman CN (1998) A Study of the Evolution of Mechanical Properties and Structural Heterogeneity of Polymer Networks Formed by Photopolymerizations of Multifunctional (Meth)Acrylates, Polymer 39:2507

    Article  CAS  Google Scholar 

  21. Yu Q, Nauman S, Santree JP, Zhu S (2001) UV Photopolymerization Behavior of Dimethacrylate Oligomers with Camphorquinone/Amine Initiator System, J. Appl. Polym. Sci. 82:1107

    Article  CAS  Google Scholar 

  22. Barbeau P, Gerard JF, Pascault JP, Vigier G (1999) Morphological Analysis of Photocured Polyurethane Acrylate Networks. Correlation with Viscoelastic Properties, J. Polym. Sci. B: Polym. Phys. 37:919

    Article  CAS  Google Scholar 

  23. Myers RH, Montgomery DC (2002) Response Surface Methodology, Process and Product Optimization using Designed Experiments. John Wiley and Sons, New York

    Google Scholar 

  24. Del Vecchio RJ (1977) Understanding Design of Experiments: A Primer for Technologists, Hanser/Gardner, Cincinnati

    Google Scholar 

  25. Misev TA (1989) Calculating Technique for Formulating Hydroxyl-Terminated Polyesters Based on Blends of Polyols and Polyacids, J. Coat. Technol. 61(772):49–52

    CAS  Google Scholar 

  26. Ballard RL, Sailer RA, Larson B, Soucek MD (2001) Fracture Toughness of Inorganic–Organic Hybrid Coatings, J. Coat. Technol. 73(913):107–114

    Article  CAS  Google Scholar 

  27. Jordens K, Wilkes G (2001) Transparent, Abrasion-Resistant Coatings for Metal Substrates, J. Macromol. Sci. Chem. A38:185

    CAS  Google Scholar 

  28. Allen PEM, Simon GP, Williams DRG, Williams EH (1989) Dynamic Mechanical Properties and Cross-Polarized, Proton-Enhanced, Magic Angle Spinning Carbon-13 NMR Time Constants of Poly[Oligo(Ethylene Glycol)Dimethacrylates]. Macromolecules 22:809

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mark D. Soucek.

Additional information

Presented at the 27th Biennial Western Coatings Societies Symposium & Show and FSCT Annual Meeting held in Las Vegas, NV, on November 6–9, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nebioglu, A., Soucek, M.D. Investigation of the properties of UV-curing acrylate-terminated unsaturated polyester coatings by utilizing an experimental design methodology. J Coat Technol Res 4, 425–433 (2007). https://doi.org/10.1007/s11998-007-9035-y

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-007-9035-y

Keywords

Navigation