Fats from Chemically Interesterified High-Oleic Sunflower Oil and Fully Hydrogenated Palm Oil

  • Monise Helen Masuchi
  • Kelly Moreira Gandra
  • André Luis Marangoni
  • Cristiane de Sá Perenha
  • Ming Chih Chiu
  • Renato Grimaldi
  • Lireny Aparecida Guaraldo Gonçalves
Original Paper

DOI: 10.1007/s11746-014-2420-7

Cite this article as:
Masuchi, M.H., Gandra, K.M., Marangoni, A.L. et al. J Am Oil Chem Soc (2014) 91: 859. doi:10.1007/s11746-014-2420-7
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Abstract

Chemical interesterification of different lipid materials has considerable potential for the production of a wide variety of special fats with improved functional and nutritional properties. The present study aimed to evaluate the chemical interesterification of blends of high-oleic sunflower oil (HOSO) and fully hydrogenated palm oil (FHPO) in the ratios (% w/w) of 80:20, 70:30, 60:40 and 50:50. The blends were characterized in triacylglycerol composition, melting point, solid fat content and crystallization behavior, and some applications in food products were suggested. The interesterification altered the solid fat content, melting point and crystallization isotherm of the samples, after the levels of trisaturated triacylglycerols decreased and disaturated–monounsaturated and monosaturated–diunsaturated triacylglycerol contents increased, due to the randomization of fatty acids. The modification in the triacylglycerol composition promoted greater miscibility between the HOSO and FHPO fractions, creating new application possibilities for the food industry.

Keywords

Chemical interesterification Triacylglycerol composition Palm oil High oleic sunflower oil Crystallization behavior 

Copyright information

© AOCS 2014

Authors and Affiliations

  • Monise Helen Masuchi
    • 1
  • Kelly Moreira Gandra
    • 2
  • André Luis Marangoni
    • 2
  • Cristiane de Sá Perenha
    • 3
  • Ming Chih Chiu
    • 2
  • Renato Grimaldi
    • 2
  • Lireny Aparecida Guaraldo Gonçalves
    • 2
  1. 1.School of Chemical EngineeringUniversity of Campinas (UNICAMP)CampinasBrazil
  2. 2.School of Food EngineeringUniversity of Campinas (UNICAMP)CampinasBrazil
  3. 3.Kerry Ingredients and Flavors, R&DCampinasBrazil