Gibbs Energy of Formation of MnO: Measurement and Assessment
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- Jacob, K.T., Kumar, A. & Waseda, Y. J Phs Eqil and Diff (2008) 29: 222. doi:10.1007/s11669-008-9280-5
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The new data are in excellent agreement with the earlier measurements of Alcock and Zador. Grundy et al. incorrectly analyzed the data of Alcock and Zador showing relatively large difference (±5 kJ mol−1) in Gibbs energies of MnO from their two cells with Fe + Fe1 − δO and Ni + NiO as reference electrodes. Thermodynamic data for MnO is reassessed in the light of the new measurements. A table of refined thermodynamic data for MnO from 298.15 to 2000 K is presented.