Abstract
Cold spraying was applied to deposit Ti2AlC on different substrate materials. The study of single impacts by scanning electron microscopy indicates that bonding of the first layer is mainly attributed to the deformation and shear instabilities occurring at substrate sites. Nevertheless, as compared to the feedstock particles, the splats appear flattened by the impact. This deformation seems to be attributed not only to local, internal shear but also to internal fracture. By applying up to five passes under optimized spray parameters, Ti2AlC-coatings with thicknesses of about 110-155 μm were achieved. XRD analysis of the coating proved that the crystallographic structure of the feedstock was retained during cold spraying. The coating microstructures show rather low porosity of about <2%, but several cracks between spray layers. Successful build-up of more than one layer can probably be attributed to local deformation of the highly anisotropic Ti2AlC-phase.
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References
M.W. Barsoum and T. El-Raghy, The MAX Phases: Unique New Carbide and Nitride Materials, Am. Sci., 2001, 4(89), p 334-343
M.W. Barsoum and M. Radovic, Elastic and Mechanical Properties of the MAX Phases, Annu. Rev. Mater. Res., 2011, 41, p 195-227
P. Eklund, M. Beckers, U. Jansson, H. Högberg, and L. Hultman, The Mn+1AXn Phases: Materials Science and Thin-Film Processing, Thin Solid Films, 2010, 518, p 1851-1878
J. Jiang, A. Fasth, P. Nylén, and W.B. Choi, Microindentation and Inverse Analysis to Characterize Elastic-Plastic Properties for Thermal Sprayed Ti2AlC and NiCoCrAlY, J. Therm. Spray Technol., 2009, 18(2), p 194-200
J. Frodelius, M. Sonestedt, S. Björklund, J.-P. Palmquist, K. Stiller, H. Högberg, and L. Hultman, Ti2AlC Coatings Deposited by High Velocity Oxy-Fuel Spraying, Surf. Coat. Technol., 2008, 202(24), p 5976-5981
H. Assadi, F. Gärtner, T. Stoltenhoff, and H. Kreye, Bonding Mechanism in Cold Gas Spraying, Acta Mater., 2003, 51(15), p 4379-4394
T. Schmidt, F. Gärtner, H. Assadi, and H. Kreye, Development of a Generalized Parameter Window for Cold Spray Deposition, Acta Mater., 2006, 54(3), p 729-742
J.-O. Kliemann, H. Gutzmann, F. Gärtner, H. Hübner, C. Borchers, and T. Klassen, Formation of Cold-Sprayed Ceramic Titanium Dioxide Layers on Metal Surfaces, J. Therm. Spray Technol., 2010, 20(1-2), p 292-298
M. Yamada, Y. Kandori, S. Kazunori, and M. Fukumoto, Fabrication of Titanium Dioxide Photocatalyst Coatings by Cold Spray, J. Solid Mech. Mater. Eng., 2009, 3(2), p 210-216
A. List, F. Gärtner, T. Schmidt and T. Klassen, Impact Conditions for Cold Spraying of Hard Metallic Glasses, J. Therm. Spray Technol., 2012, 21(3-4). doi:10.1007/s11666-012-9750-5
J.-O. Kliemann, Kaltgasspritzen photokatalytisch aktiver Titandioxidbeschichtungen, Ph.D. Thesis, Helmut Schmidt University, 2012
O. Wilhelmsson, J.P. Palmquist, E. Lewin et al., Deposition and Characterization of Ternary Thin Films Within the Ti-Al-C System by DC Magnetron Sputtering, J. Cryst. Growth, 2006, 291(1), p 290-300
V. Maurice, G. Despert, S. Zanna, P. Josso, M.P. Bacos, and P. Marcus, XPS Study of the Initial Stages of Oxidation of α2-Ti3Al and γ-TiAl Intermetallic Alloys, Acta Mater., 2007, 55(10), p 3315-3325
B. Timmermans, N. Vaeck, A. Hubin, and F. Reniers, Chemical Effects in Auger Electron Spectra of Aluminium, Surf. Interface Anal., 2002, 34(1), p 356-359
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The authors would like to thank the laboratory staff, in alphabetical order Thomas Breckwoldt, Dieter Müller, Norbert Németh, Camilla Schulze, Matthias Schulze, and Uwe Wagener for their support in the presented work.
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Gutzmann, H., Gärtner, F., Höche, D. et al. Cold Spraying of Ti2AlC MAX-Phase Coatings. J Therm Spray Tech 22, 406–412 (2013). https://doi.org/10.1007/s11666-012-9843-1
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DOI: https://doi.org/10.1007/s11666-012-9843-1