Journal of Thermal Spray Technology

, 18:572

Characterization of Plasma-Sprayed Yttria-Stabilized Zirconia Coatings by Cathodoluminescence

  • Georg Mauer
  • Doris Sebold
  • Robert Vaßen
  • Detlev Stöver
Peer Reviewed

DOI: 10.1007/s11666-009-9370-x

Cite this article as:
Mauer, G., Sebold, D., Vaßen, R. et al. J Therm Spray Tech (2009) 18: 572. doi:10.1007/s11666-009-9370-x

Abstract

The occurrence of monoclinic zirconia phase has an important impact on the performance of thermal barrier coatings (TBC) of yttria-stabilized zirconia (YSZ). Therefore, a reliable method is needed to detect its contents and to investigate also its spatial distribution within the parent microstructure. This was the motivation to apply cathodoluminescence (CL) spectroscopy. YSZ coatings with different porosities were manufactured by atmospheric plasma spraying. CL analysis yielded monoclinic phase contents of 5.2 ± 1.6% for the high-porous sample and 3.4 ± 0.5% for the low-porous sample. The results were qualitatively confirmed by x-ray diffraction (XRD). However, due to its lower detection sensitivity the XRD results are quantitatively on lower level. Owing to its synthesis method, the applied powder feedstock showed a considerable content of monoclinic phase. The lower the particle temperatures were the larger fraction of monoclinic phase remained untransformed. This has to be considered when spraying high-porous TBCs.

Keywords

cathodoluminescensemonoclinic phaseplasma sprayingthermal barrier coatingsyttria-stabilized zirconia (YSZ)

Copyright information

© ASM International 2009

Authors and Affiliations

  • Georg Mauer
    • 1
  • Doris Sebold
    • 1
  • Robert Vaßen
    • 1
  • Detlev Stöver
    • 1
  1. 1.Institut für Energieforschung IEF-1Forschungszentrum Jülich GmbHJülichGermany