Ionics

, Volume 19, Issue 4, pp 657–663

Highly sensitive electrochemical detection of adenine on a graphene-modified carbon ionic liquid electrode

Authors

    • College of Chemistry and Chemical EngineeringHainan Normal University
    • College of Chemistry and Molecular EngineeringQingdao University of Science and Technology
  • Jun Liu
    • College of Chemistry and Molecular EngineeringQingdao University of Science and Technology
  • Xiaomei Ju
    • College of Chemistry and Molecular EngineeringQingdao University of Science and Technology
  • Le Zhang
    • College of Chemistry and Molecular EngineeringQingdao University of Science and Technology
  • Xiaowei Qi
    • College of Chemistry and Molecular EngineeringQingdao University of Science and Technology
  • Ni Hui
    • College of Chemistry and PharmacyQingdao Agriculture University
Original Paper

DOI: 10.1007/s11581-012-0789-6

Cite this article as:
Sun, W., Liu, J., Ju, X. et al. Ionics (2013) 19: 657. doi:10.1007/s11581-012-0789-6

Abstract

A new electrochemical method for the sensitive detection of adenine was established on a chitosan (CTS)- and graphene (GR)-modified carbon ionic liquid electrode (CILE). CILE was prepared by mixing 1-butylpyridinium hexafluorophosphate (BPPF6) and paraffin with graphite powder. Due to the synergistic effects of GR, CILE, and the interaction of GR with IL on the electrode surface, the electrochemical performance of CTS/GR/CILE were greatly enhanced. Electrochemical behaviors of adenine on the modified electrode was investigated with a single well-defined oxidation peak appeared. The electrochemical reaction of adenine was an adsorption-controlled irreversible process, and the electrochemical parameters were further calculated. Under the optimal conditions, the oxidation peak current was proportional to adenine concentration in the range from 1.0 nmol L−1 to 70.0 μmol L−1 with a detection limit of 0.286 nmol L−1 (3σ) by differential pulse voltammetry. The established method showed the advantages such as good selectivity, stability, and repeatability.

Keywords

Adenine Graphene 1-Butylpyridinium hexafluorophosphate Cyclic voltammetry

Copyright information

© Springer-Verlag 2012