Abstract
A novel method is presented for complex structure fabrication, which is capable of breaking the hexagonal symmetry of the conventional colloid sphere lithography via the interferometric illumination of colloid sphere monolayers (IICSM). It is demonstrated that the perfect lateral synchronization of a linear intensity modulation originating from two-beam interference with respect to a hexagonal colloid sphere monolayer makes it possible to tune four complex structure parameters independently. Based on comparative study of hexagonal and rectangular hole doublet-arrays, which can be generated by linearly polarized light via homogeneous illumination and via IICSM, it is shown that the novel IICSM method enables plasmonic spectral engineering with higher degrees of freedom. The unique spectral properties of the complex patterns attainable via IICSM are more precisely tunable by properly selected azimuthal orientation during illumination and by the surrounding medium. It is shown that coupling phenomena between propagating and localized plasmonic modes on appropriately designed complex structures result in unique charge and near-field distribution accompanied by narrow Fano lines. Optimal configurations of complex plasmonic structures consisting of a rectangular array of hole doublets with different geometrical size parameters are presented, which ensure enhanced sensitivity in bio-detection.
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References
Wannemacher R (2001) Plasmon-supported transmission of light through nanometric holes in metallic thin films. Opt Commun 195:107–118
Yin L, Vlasko-Vlasov VK, Rydh A, Pearson J, Welp U, Chang S-H, Gray SK, Schatz GC, Brown DB, Kimball CW (2004) Surface plasmons at single nanoholes in Au films. Appl Phys Lett 85(3):467–469
Degiron A, Lezec HJ, Yamamoto N, Ebbesen TW (2004) Optical transmission properties of a single subwavelength aperture in a real metal. Opt Commun 239:61–66
Zakharian AR, Mansuripur M, Moloney JV (2004) Transmission of light through small elliptical apertures. Opt Express 12:2631–2648
Chang S-H, Gray SK, Schatz GC (2005) Surface plasmon generation and light transmission by isolated nanoholes and arrays of nanoholes in thin metal films. Opt Express 13:3150–3165
Rindzevicius T, Alaverdyan Y, Sepulveda B, Pakizeh T, Käll M, Hillenbrand R, Aizpurua J, de Abajo FJ G (2007) Nanohole plasmons in optically thin gold films. J Phys Chem C 111:1207–1212
Sepúlveda B, Alaverdyan Y, Alegret J, Käll M, Johansson P (2008) Shape effects in the localized surface plasmon resonance of single nanoholes in thin metal films. Opt Express 16:5609–5616
Kelly KL, Coronado E, Zhao LL, Schatz GC (2003) The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment. J Phys Chem B 107:668–677
Sherry L, Chang S-H, Schatz G, Van Duyne R (2005) Localized surface plasmon resonance spectroscopy of single silver nanocubes. Nano Lett 5:2034–2038
Ebbesen TW, Lezec HJ, Ghaemi HF, Thio T, Wolff PA (1998) Extraordinary optical transmission through sub-wavelength hole arrays. Nature 391:667–669
Ghaemi HF, Thio T, Grupp DE, Ebbesen TW, Lezec HJ (1998) Surface plasmons enhance optical transmission through subwavelength holes. Phys Rev B 58(11):6779–6782
Thio T, Ghaemi HF, Lezec HJ, Wolff PA, Ebbesen TW (1999) Surface-plasmon-enhanced transmission through hole arrays in Cr films. J Opt Soc Am B 16:1743–1748
Martín-Moreno L, García-Vidal FJ, Pellerin KM, Thio T, Pendry JB, Ebbesen TW (2001) Theory of extraordinary optical transmission through subwavelength hole arrays. Phys Rev Lett 86(6):1114–1117
Klein Koerkamp KJ, Enoch S, Segerink FB, van Hulst NF, Kuipers L (2004) Strong influence of hole shape on extraordinary transmission through periodic arrays of subwavelength holes. Phys Rev Lett 92:183901
Gordon R, Brolo AG, McKinnon A, Rajora A, Leathem B, Kavanagh KL (2004) Strong polarization in the optical transmission through elliptical nanohole arrays. Phys Rev Lett 92(3):037401
Barnes WL, Murray WA, Dintinger J, Devaux E, Ebbesen TW (2004) Surface plasmon polaritons and their role in the enhanced transmission of light through periodic arrays of subwavelength holes in a metal film. Phys Rev Lett 92(10):107401
Prikulis J, Hanarp P, Olofsson L, Sutherland D, Kall M (2004) Optical spectroscopy of nanometric holes in thin gold films. Nano Lett 4(6):1003–1007
Degiron A, Ebbesen TW (2005) The role of localized surface plasmon modes in the enhanced transmission of periodic subwavelength apertures. J Opt A Pure Appl Opt 7:S90
De Abajo FJG, Gómez-Medina R, Sáenz JJ (2005) Full transmission through perfect-conductor subwavelength hole arrays. Phys Rev E 72:016608
Altewischer E, Genet C, van Exter MP, Woerdman JP, Alkemade PFA, van Zuuk A, van der Drift EWJM (2005) Polarization tomography of metallic nanohole arrays. Opt Lett 30:90–92
DiMaio JR, Ballato J (2006) Polarization-dependent transmission through subwavelength anisotropic aperture arrays. Opt Express 14:2380–2384
Genet C, Ebbesen TW (2007) Light in tiny holes. Nature 445:39–46
De Abajo FJG (2007) Light scattering by particle and hole arrays. Rev Mod Phys 79(4):1267–1290
Pacifici D, Lezec HJ, Sweatlock LA, Walters RJ, Atwater HA (2008) Universal optical transmission features in periodic and quasiperiodic hole arrays. Opt Express 16(12):9222–9238
Parsons WJ, Hendry E, Burrows CB, Auquié B, Sambles JR, Barnes WL (2009) Localized surface-plasmon resonances in periodic nondiffracting metallic nanoparticle and nanohole arrays. Phys Rev B 79(7):073412
Garcia-Vidal FJ, Martin-Moreno L, Ebbesen TW, Kuipers L (2010) Rev Mod Phys 82:729–787
Chanda D, Shigeta K, Truong T, Lui E, Mihi A, Schulmerich M, Braun PV, Bhargava R, Rogers JA (2011) Coupling of plasmonic and optical cavity modes in quasi-three-dimensional plasmonic crystals. Nat Commun 2:479
Genet C, van Exter MP, Woerdman JP (2003) Fano-type interpretation of red shifts and red tails in hole array transmission spectra. Opt Commun 225:331–336
Sarrazin M, Vigneron J-P, Vigoureux J-M (2003) Role of Wood anomalies in optical properties of thin metallic films with a bidimensional array of subwavelength holes. Phys Rev B 67:085415
Hao F, Sonnefraud Y, Dorpe PV, Maier SA, Halas NJ, Nordlander P (2008) Symmetry breaking in plasmonic nanocavities: subradiant LSPR sensing and a tunable Fano resonance. Nano Lett 8(11):3983–3988
Verellen N, Sonnefraud Y, Sobhani H, Hao F, Moshchalkov VV, Dorpe PV, Nordlander P, Maier SA (2009) Fano resonances in individual coherent plasmonic nanocavities. Nano Lett 9(4):1663–1667
Luk’yanchuk B, Zheludev NI, Maier SA, Halas NJ, Nordlander P, Giessen H, Chong CT (2010) The Fano resonance in plasmonic nanostructures and metamaterials. Nat Mater 9:707–715
Lassiter JB, Sobhani H, Fan JA, Kundu J, Capasso F, Nordlander P, Halas NJ (2010) Fano resonances in plasmonic nanoclusters: geometrical and chemical tunability. Nano Lett 10(8):3184–3189
Fan JA, Bao K, Wu C, Bao J, Bardhan R, Halas NJ, Manoharan VN, Shvets G, Nordlander P, Capasso F (2010) Fano-like interference in self-assembled plasmonic quadrumer clusters. Nano Lett 10:4680–4685
Rahmani M, Lukiyanchuk B, Ng B, Tavakkoli KGA, Liew YF, Hong MH (2011) Generation of pronounced Fano resonances and tuning of subwavelength spatial light distribution in plasmonic pentamers. Opt Express 19:4949–4956
Lassiter JB, Sobhani H, Knight MW, Mielczarek WS, Nordlander P, Halas NJ (2012) Designing and deconstructing the fano lineshape in plasmonic nanoclusters. Nano Lett 12(2):1058–1062
Stark PR, Halleck AE, Larson DN (2005) Short order nanohole arrays in metals for highly sensitive probing of local indices of refraction as the basis for a highly multiplexed biosensor technology. Methods 37(1):37–47
Dintinger J, Klein S, Bustos F, Barnes WL, Ebbesen TW (2005) Strong coupling between surface plasmon-polaritons and organic molecules in subwavelength hole arrays. Phys Rev B 71:035424
Tetz KA, Pang L, Fainman Y (2006) High resolution surface plasmon resonance sensor based on linewidth-optimized nanohole array transmittance. Opt Lett 31(10):1528–1530
Lesuffleur A, Im H, Lindquist NC, Oh S-H (2007) Periodic nanohole arrays with shape-enhanced plasmon resonance as real-time biosensors. Appl Phys Lett 90:243110
Gordon R, Sinton D, Kavanagh KL, Brolo AG (2008) A new generation of sensors based on extraordinary optical transmission. Acc Chem Res 41:1049–1057
Hwang GM, Pang L, Mullen EH, Fainman Y (2008) Plasmonic sensing of biological analytes through nanoholes. IEEE Sensor J 8:2074–2079
Sannomiya T, Scholder O, Jefimovs K, Hafner C, Dahlin AB (2011) Investigation of plasmon resonances in metal films with nanohole arrays for biosensing applications. Small 12:1653–1663
Zhao X-M, Xia Y, Whitesides GM (1997) Soft lithographic methods for nano-fabrication. J Mater Chem 7(7):1069–1074
Xia Y, Rogers JA, Paul KE, Whitesides GM (1999) Unconventional methods for fabricating and patterning nanostructures. Chem Rev 99(7):1823–1848
Gates BD, Xu Q, Stewart M, Ryan D, Wilson CG, Whitesides GM (2005) New approaches to nanofabrication: molding, printing, and other techniques. Chem Rev 105:1171–1196
Bauerle D (1996) Laser processing and chemistry. Springer, Berlin
Kelly MK, Dahlheimer B (1996) Extended resolution for lateral structuring with laser interference gratings using high-index input coupling. Phys Status Solidi A 156:k13–k16
Csete M, Zs B (1998) Laser-induced periodic surface structure formation on polyethylene-terephthalate. Appl Surf Sci 133(1–2):5–16
Daniel C, Mücklich F, Liu Z (2003) Periodical micro-nano-structuring of metallic surfaces by interfering laser beams. Appl Surf Sci 208–209:317–321
Yu F, Li P, Shen H, Mathur S, Lehrb C-M, Bakowsky U, Mücklich F (2005) Laser interference lithography as a new and efficient technique for micropatterning of biopolymer surface. Biomaterials 26:2307–2312
Lim CS, Hong MH, Lin Y, Xie Q, Luk’yanchuk BS, Kumar AS, Rahman M (2006) Microlens array fabrication by laser interference lithography for super-resolution surface nanopatterning. Appl Phys Lett 89:191125
Csete M, Kőházi-Kis A, Cs V, Sipos Á, Szekeres G, Deli M, Osvay K, Zs B (2007) Atomic force microscopical and surface plasmon resonance spectroscopical investigation of sub-micrometer metal gratings generated by UV laser based two-beam interference in Au-Ag bimetallic layers. Appl Surf Sci 253(19):7662–7671
Burmeister F, Schafle C, Matthes T, Böhmisch M, Boneberg J, Leiderer P (1997) Colloid monolayers as versatile lithographic masks. Langmuir 13:2983–2987
Yu J, Geng C, Zheng L, Ma Z, Tan T, Wang X, Yan Q, Shen D (2012) Preparation of high-quality colloidal mask for nanosphere lithography by a combination of air/water interface self-assembly and solvent vapor annealing. Langmuir 28:12681–12689
Vogel N, Weiss CK, Landfester K (2012) From soft to hard: the generation of functional and complex colloidal monolayers for nanolithography. Soft Matter 8:4044
Kuo C-W, Shiu J-Y, Cho Y-H, Chen P (2003) Fabrication of large-area periodic nanopillar arrays for nanoimprint lithography using polymer colloid masks. Adv Mater 15:1064–1068
Cui Y, Björk MT, Liddle JA, Sönnichsen C, Boussert B, Alivisatos AP (2004) Integration of colloidal nanocrystals into lithographically patterned devices. Nano Lett 4:1094–1098
Smoukov SK, Gangwal S, Marquez M, Velev OD (2009) Reconfigurable responsive structure assembled from magnetic Janus particles. Soft Matter 5:1285–1292
Rycenga M, Camargo PHC, Xia Y (2009) Template-assisted self-assembly: a versatile approach to complex micro- and nanostructures. Soft Matter 5:1129–1136
Nedyalkov NN, Takada H, Obara M (2006) Nanostructuring of silicon surface by femtosecond laser pulse mediated with enhanced near-field of gold nanoparticles. Appl Phys A 85:163–168
Nedyalkov N, Sakai T, Miyanishi T, Obara M (2006) Near field properties in the vicinity of gold nanoparticles placed on various substrates for precise nanostructuring. J Phys D 39:5037
Atanasov PA, Nedyalkov NN, Sakai T, Obara M (2007) Localization of the electromagnetic field in the vicinity of gold nanoparticles: surface modification of different substrates. Appl Surf Sci 254:794–798
Csete M, Sipos Á, Szalai A, Szabó G (2012) Theoretical study on interferometric illumination of gold colloid sphere monolayers to produce complex structures for spectral engineering. IEEE Photon J 4(5):1909–1921
Sipos Á, Szalai A, Csete M (2012) Integrated lithography to prepare arrays of rounded nano-objects In: William M Tong, Douglas J. Resnick (ed) Alternative Lithographic Technologies IV., Proceedings of SPIE 8323, SPIE-The International Society for Optical Engineering. SPIE, Belingham, WA, pp. 83232E-1-83232E-10
Sipos Á, Szalai A, Csete M (2013) Integrated lithography to prepare periodic arrays of nano-objects. Appl Surf Sci 278(1):330–335
Born M, Wolf E (1986) Principles of optics. Pergamon Press, Oxford
Bass M (ed) (1995) Handbook of optics, 2nd edn. McGraw & Hill, New York
Palik E (ed) (1998) Handbook of optical constants of solids. Academic, San Diego
Acknowledgments
The publication has been supported by the European Union and co-funded by the European Social Funds, with a project title “Impulse lasers for use in materials science and biophotonics” and a project number TÁMOP-4.2.2.A-11/1/KONV-2012-0060 and project title “Supercomputer, the national virtual lab” and project number TÁMOP-4.2.2.C/11/1/KONV/2012-0010.
Áron Sipos contributed to the paper by preparing the models, realizing computations, and analyzing the results; Anikó Somogyi contributed to the paper by determining the charge distribution and analyzing the near-field distribution; Gábor Szabó contributed to the initial concept of the paper by suggesting the application of two-beam interference; Mária Csete contributed to the paper with the concept of IICSM, interpreted the results, and wrote the manuscript.
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Sipos, Á., Somogyi, A., Szabó, G. et al. Plasmonic Spectral Engineering via Interferometric Illumination of Colloid Sphere Monolayers. Plasmonics 9, 1207–1219 (2014). https://doi.org/10.1007/s11468-014-9732-1
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DOI: https://doi.org/10.1007/s11468-014-9732-1