Science China Chemistry

, Volume 56, Issue 9, pp 1197–1203

Tuning the solid-state emission of the analogous GFP chromophore by varying alkyl chains in the imidazolinone ring

Articles Special Topic Aggregated-Induced Emission

DOI: 10.1007/s11426-013-4913-x

Cite this article as:
Shen, X., Huang, G., Li, K. et al. Sci. China Chem. (2013) 56: 1197. doi:10.1007/s11426-013-4913-x

Abstract

New analogues of green fluorescent protein (GFP) chromophore mGFP-Cn (n = 1, 3, 5, 11) with alkyl chains of different lengths in the imidazolinone rings were synthesized and their crystal structures were determined. These GFP-like chromophores are all emissive in the solid state. And the solid-state emission quantum yields of increase by extending the lengths of alkyl chains, owing to the fact that the intermolecular pi-pi interactions are significantly weakened based on their crystal structures.

Keywords

green fluorescent protein (GFP) chromorphoresolid-state fluorescencefluorescence modulation

Copyright information

© Science China Press and Springer-Verlag Berlin Heidelberg 2013

Authors and Affiliations

  1. 1.Beijing National Laboratory for Molecular Sciences; Key Laboratory of Organic Solids; Institute of ChemistryChinese Academy of SciencesBeijingChina
  2. 2.University of Chinese Academy of SciencesBeijingChina