Water, Air, and Soil Pollution

, Volume 198, Issue 1, pp 65–75

The Odd–Even Behaviour of Dicarboxylic Acids Solubility in the Atmospheric Aerosols

Article

DOI: 10.1007/s11270-008-9826-5

Cite this article as:
Rozaini, M.Z.H. & Brimblecombe, P. Water Air Soil Pollut (2009) 198: 65. doi:10.1007/s11270-008-9826-5

Abstract

The solubility and the enthalpy of dicarboxylic acids have been determined in water at intervals between 278.5 and 543.5 K. At 298.15 K, the values derived were: ΔsolHm (m = 1.33 mol kg−1) = 29.80 kJ mol−1for oxalic acid; ΔsolHm (m = 16.03 mol kg−1) = 12.82 kJ mol−1 for malonic acid; ΔsolHm (m = 0.75 mol kg−1) = 28.20 kJ mol−1 for succinic acid; ΔsolHm (m = 8.77 mol kg−1) = 48.01 kJ mol−1 and ΔsolHm (m = 0.17 mol kg−1) = 40.30 kJ mol−1 for glutaric and adipic acid respectively. The solubility value exhibits a prominent odd–even effect with respect to terms with even number of carbon atoms with the odd carbon numbers showing much higher solubility. Observations made in the atmospheres suggest that this odd–even effect may have implications for the relative abundance of these acids in aerosols.

Keywords

Oxalic acidMalonic acidSuccinic acidGlutaric acidAdipic acidSolubilityWater soluble aerosol

Copyright information

© Springer Science+Business Media B.V. 2008

Authors and Affiliations

  1. 1.School of Environmental ScienceUniversity of East AngliaNorwichUK
  2. 2.Department of Chemical Sciences, Faculty of Science and TechnologyUniversity Malaysia TerengganuKuala TerengganuMalaysia