Topics in Catalysis

, Volume 57, Issue 17, pp 1325–1334

Challenges in Catalytic Manufacture of Renewable Pyrrolidinones from Fermentation Derived Succinate

  • James F. White
  • Johnathan E. Holladay
  • Allan A. Zacher
  • John G. FryeJr.
  • Todd A. Werpy
Original Paper

DOI: 10.1007/s11244-014-0299-z

Cite this article as:
White, J.F., Holladay, J.E., Zacher, A.A. et al. Top Catal (2014) 57: 1325. doi:10.1007/s11244-014-0299-z

Abstract

Fermentation derived succinic acid ammonium salt is an ideal precursor for manufacture of renewable N-methyl pyrrolidinone (NMP) or 2-pyrrolidinone (2P) via heterogeneous catalysis. However, there are many challenges to making this a practical reality. Chief among the challenges is avoiding catalyst poisoning by fermentation by- and co-products. Battelle/Pacific Northwest National Laboratory have developed an effective technology strategy for this purpose. The technology is a combination of purely thermal processing, followed by simple catalytic hydrogenation that together avoids catalyst poisoning from fermentation impurities and provides high selectivity and yields of NMP or 2P.

Keywords

Succinic acid Hydrogenation N-Methyl succimide N-Methyl-2-pyrrolidinone 2-pyrrolidinone Renewable resources 

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • James F. White
    • 1
  • Johnathan E. Holladay
    • 2
  • Allan A. Zacher
    • 2
  • John G. FryeJr.
    • 2
  • Todd A. Werpy
    • 3
  1. 1.3RiversCatalysis, LLCRichlandUSA
  2. 2.Pacific Northwest National LaboratoryRichlandUSA
  3. 3.JRR Research CenterArcher-Daniels-MidlandDecaturUSA

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