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Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials

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Abstract

The interaction of 1,2-dichloroethane (DCE) vapors with bulk NiCr alloy resulting in complete metal wastage with the formation of carbon nanofibers (CNFs) has been described from mechanistic point of view. The genesis of surface transformations of the bulk NiCr alloy exposed to corrosive reaction mix Ar/H2/DCE at 550 °C was studied by AFM, SEM and TEM techniques. The mechanism of metal dusting in aggressive reaction media was suggested. The observed process has been considered as a way to produce the self-organizing Ni/CNF catalyst which is effective for further decomposition of chlorinated hydrocarbons leading to nanostructured carbon product.

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Acknowledgments

Russian Foundation for Basic Research (grant #12-03-31729) and the Department of Chemistry and Materials Sciences RAS (project #5.2.2) are acknowledged with gratitude for financial support.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

    Ilya V. Mishakov, Yuri I. Bauman & Aleksey A. Vedyagin

  2. Novosibirsk State Technical University, Novosibirsk, Russia

    Ilya V. Mishakov & Aleksey A. Vedyagin

  3. State Research Center of Virology and Biotechnology “Vector”, 630559, Koltsovo, Russia

    Denis V. Korneev

Authors
  1. Ilya V. Mishakov
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  2. Yuri I. Bauman
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  3. Denis V. Korneev
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  4. Aleksey A. Vedyagin
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Correspondence to Ilya V. Mishakov.

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Mishakov, I.V., Bauman, Y.I., Korneev, D.V. et al. Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials. Top Catal 56, 1026–1032 (2013). https://doi.org/10.1007/s11244-013-0066-6

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  • DOI: https://doi.org/10.1007/s11244-013-0066-6

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