Topics in Catalysis

, Volume 55, Issue 7, pp 565–570

Rh(III) Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange

  • J. Brannon Gary
  • Tyler J. Carter
  • Melanie S. Sanford
Original Paper

DOI: 10.1007/s11244-012-9825-z

Cite this article as:
Gary, J.B., Carter, T.J. & Sanford, M.S. Top Catal (2012) 55: 565. doi:10.1007/s11244-012-9825-z

Abstract

This report describes the synthesis of Rh(III) complexes containing a pyridinium-substituted bipyridine ligand. The catalytic activity of these complexes in H/D exchange reactions between arenes and acetic acid-d4 has been evaluated.

Keywords

C−H activationH/D exchangeRhodiumBipyridine

Supplementary material

11244_2012_9825_MOESM1_ESM.docx (1.6 mb)
Supplementary material 1 (DOCX 1662 kb)

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • J. Brannon Gary
    • 1
  • Tyler J. Carter
    • 1
  • Melanie S. Sanford
    • 1
  1. 1.Department of ChemistryUniversity of MichiganAnn ArborUSA