Original Paper

Topics in Catalysis

, Volume 55, Issue 7, pp 565-570

First online:

Rh(III) Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange

  • J. Brannon GaryAffiliated withDepartment of Chemistry, University of Michigan
  • , Tyler J. CarterAffiliated withDepartment of Chemistry, University of Michigan
  • , Melanie S. SanfordAffiliated withDepartment of Chemistry, University of Michigan Email author 

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Abstract

This report describes the synthesis of Rh(III) complexes containing a pyridinium-substituted bipyridine ligand. The catalytic activity of these complexes in H/D exchange reactions between arenes and acetic acid-d4 has been evaluated.

Keywords

C−H activation H/D exchange Rhodium Bipyridine