, Volume 52, Issue 13-20, pp 1799-1802
Date: 10 Jul 2009

Flame-Made Pt/K/Al2 O3 for NO x Storage–Reduction (NSR) Catalysts

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Abstract

High surface area Pt/K/Al2O3 catalysts were prepared with a 2-nozzle flame spray method resulting in Pt clusters on γ-Al2O3 and amorphous K storage material as evidenced by Raman spectroscopy. The powders had a high NO x storage capacity and were regenerated fast in a model exhaust gas environment. From 300 to 400 °C no excess NO x was detected in the off gas during transition from fuel lean to fuel rich conditions, resulting in a highly effective NO x removal performance. Above 500 °C, the NSR activity was lost and not recovered at lower temperatures as K-compounds were partially crystallized on the catalyst.