Topics in Catalysis

, Volume 44, Issue 1, pp 319–324

Effect of gold addition on Pt and Pd catalysts in liquid phase oxidations

  • Laura Prati
  • Alberto Villa
  • Claudio Campione
  • Paolo Spontoni
Article

DOI: 10.1007/s11244-007-0305-9

Cite this article as:
Prati, L., Villa, A., Campione, C. et al. Top Catal (2007) 44: 319. doi:10.1007/s11244-007-0305-9

Single phase Au–Pd and Au–Pt on carbon catalysts have been compared in the liquid phase oxidation of glycerol (representative for polyols) and n-octanol (representative for long chain aliphatic alcohol). The observed overall enhancement of catalytic activity appeared to be function of support, substrate and reaction conditions. Effect of substrate structure has been disentangled: synergistic effect between Au and Pt was maximized when polyol-like substrates were oxidized whereas Au–Pd based catalyst showed a more general match.

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Laura Prati
    • 1
  • Alberto Villa
    • 1
  • Claudio Campione
    • 1
  • Paolo Spontoni
    • 1
  1. 1.Dipartimento di Chimica Inorganica Metallorganica e Analitica and INSTM Unit, Centre of Excellence CIMAINAUniversità di MilanoMilanItaly