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Vanadium oxide surfaces and supported vanadium oxide nanoparticles

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The information obtained from the characterization of vanadium oxide single crystal surfaces is related to the study of vanadia nanoparticles supported on silica and alumina thin films, model systems for the so-called “supported monolayer vanadia catalysts”. It is found that these particles have properties similar to V2O3 surfaces, where the topmost V ions are involved in vanadyl groups and have a 5+ oxidation state. A vibrational spectroscopy investigation combined with DFT calculations show that the accepted interpretation of vibrational spectra from vanadia catalysts must be revised.

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Authors and Affiliations

  1. Department Chemical Physics, Fritz-Haber-Institut der MPG, Faradayweg 4-6, D-14195, Berlin, Germany

    S. Guimond, M. Abu Haija, S. Kaya, J. Lu, J. Weissenrieder, S. Shaikhutdinov, H. Kuhlenbeck & H.-J. Freund

  2. Institute of Chemistry, Humboldt-Universität zu Berlin, Unter den Linden 6, D-10099, Berlin, Germany

    J. Döbler & J. Sauer

Authors
  1. S. Guimond
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  2. M. Abu Haija
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  3. S. Kaya
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  4. J. Lu
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  5. J. Weissenrieder
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  6. S. Shaikhutdinov
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  7. H. Kuhlenbeck
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  8. H.-J. Freund
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  9. J. Döbler
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  10. J. Sauer
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Correspondence to H.-J. Freund or J. Sauer.

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Guimond, S., Abu Haija, M., Kaya, S. et al. Vanadium oxide surfaces and supported vanadium oxide nanoparticles. Top Catal 38, 117–125 (2006). https://doi.org/10.1007/s11244-006-0076-8

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