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Triangular ruthenium acetate clusters containing the bis(pyridyl)propane ligand and their inclusion chemistry with β-cyclodextrin

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An Erratum to this article was published on 21 October 2011

Abstract

The triruthenium carboxylate cluster [Ru3O(OAc)6(py)2(bpp)]+ (OAc = acetate) containing the bridging 1,3-bis(4-pyridyl)propane (bpp) ligand, and its dimeric species [{Ru3O(OAc)6(py2)}2(μ-bpp)]2+ were synthesized in order to investigate their inclusion compounds with β-cyclodextrin (β-CD). Characterization of the complexes was carried out based on spectroscopic, electrochemical and spectroelectrochemical techniques, while the formation of inclusion complexes was evaluated using 1H NMR/NOESY spectroscopy. Since bpp is a flexible ligand, a DFT study was carried out in order to characterize its conformational isomers and their possible role in the host–guest chemistry with β-CD. Instead of observing the formation of inclusion compounds with different stoichiometries, we observed the formation of 1:1 bpp/β-CD compounds in which the bpp ligand assumes different conformations. The assembly of polymetallic rotaxane species was successfully demonstrated by monitoring the 1H NMR spectra of the monomeric cluster species in the presence of aquapentacyanoferrate(II) ions and β-CD.

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Acknowledgments

The support from FAPESP (Fundação de Amparo à Pesquisa do Estado de São Paulo), CNPq (Conselho Nacional de Pesquisa), and CAPES (Coordenação de Aperfeiçoamento de Pessoal de Nível Superior) are gratefully acknowledged.

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Authors and Affiliations

  1. Departamento de Física e Química, Faculdade de Ciências Farmacêuticas de Ribeirão Preto da Universidade de São Paulo, Av. do Café s/número, Ribeirão Preto, 14090-903, Brazil

    Sofia Nikolaou

  2. Instituto de Química da Universidade de São Paulo—USP, P.O. BOX 26077, São Paulo, 05513-970, Brazil

    Sérgio Hiroshi Toma, Juliano B. Alves, Koiti Araki & Henrique Eisi Toma

  3. Universidade Estadual de Maringá, Av. Colombo 5.790, Maringá, 87020-900, Brazil

    Vagner Roberto de Souza

Authors
  1. Sofia Nikolaou
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  2. Sérgio Hiroshi Toma
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  3. Vagner Roberto de Souza
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  4. Juliano B. Alves
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  5. Koiti Araki
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  6. Henrique Eisi Toma
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Corresponding authors

Correspondence to Sofia Nikolaou or Henrique Eisi Toma.

Additional information

An erratum to this article can be found at http://dx.doi.org/10.1007/s11243-011-9551-6

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Nikolaou, S., Toma, S.H., de Souza, V.R. et al. Triangular ruthenium acetate clusters containing the bis(pyridyl)propane ligand and their inclusion chemistry with β-cyclodextrin. Transition Met Chem 36, 775–783 (2011). https://doi.org/10.1007/s11243-011-9532-9

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  • DOI: https://doi.org/10.1007/s11243-011-9532-9

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