, Volume 32, Issue 7, pp 877-883
Date: 02 Aug 2007

Synthesis and reactivity of N,N-bis(diphenylphosphino)dimethylaniline compounds

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Abstract

New chalcogenides and complexes of N,N-bis(diphenylphosphino)dimethylanilines were prepared by the reaction of N,N-bis(diphenylphosphino)dimethylaniline ligands with aqueous H2O2, elemental S and Se and transition metal complexes based on Cu, Pd and Pt. All the new compounds have been characterised by spectroscopy and the molecular structures of the three complexes of N,N-bis(diphenylphosphino)dimethylanilines have been determined by X-ray crystallography.